Formation of copper(I)-templated [2]rotaxanes using “click” methodology: influence of the base, the thread and the catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

Fabien Durola, Stéphanie Durot, Valérie Heitz, Antoine Joosten, Jean-Pierre Sauvage, Yann Trolez

ABSTRACT

Three new copper(I)-assembled [2]rotaxanes incorporating the same macrocycle and different axes containing a bipy, a phen or a terpy have been synthesized thanks to CuAAC reaction for attaching the stoppers. The influence of the nature of the base used for the stoppering reaction was investigated on the formation of the bipy-containing rotaxane. The yield of the [2]rotaxane synthesis was increased when using a phen as a coordinating unit in the thread with [Cu(CH3CN)4](PF6) as catalyst. The strong influence of the nature of the catalyst was clearly evidenced for the formation of the terpy rotaxane, increasing the yield of the stoppering reaction from 0 to 95% by just substituting the Cu(I) catalyst. Finally, the best conditions found for our systems are the use of Na2CO3 as a base and Cu(tren′)Br as a catalyst. More... »

PAGES

507-515

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10847-011-9986-6

DOI

http://dx.doi.org/10.1007/s10847-011-9986-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024325005


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Durola", 
        "givenName": "Fabien", 
        "id": "sg:person.0635260774.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0635260774.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Durot", 
        "givenName": "St\u00e9phanie", 
        "id": "sg:person.0672270631.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0672270631.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Heitz", 
        "givenName": "Val\u00e9rie", 
        "id": "sg:person.01362476351.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01362476351.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Joosten", 
        "givenName": "Antoine", 
        "id": "sg:person.0642450561.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642450561.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sauvage", 
        "givenName": "Jean-Pierre", 
        "id": "sg:person.01025725303.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025725303.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut de Chimie de Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.462043.7", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trolez", 
        "givenName": "Yann", 
        "id": "sg:person.0710563761.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0710563761.29"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/1521-3773(20001002)39:19<3348::aid-anie3348>3.0.co;2-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001814930"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200800480", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003547937"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0018264", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007365527"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0018264", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007365527"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.80.1856", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010089936"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201002220", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011330717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1nj20213h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015321352"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar000174l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016430619"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar000174l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016430619"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.inoche.2010.01.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017122903"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b9nj00278b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019633258"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b9nj00278b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019633258"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja056903f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020434230"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja056903f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020434230"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200902649", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024949533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200902649", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024949533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028820752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo011148j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032319128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo011148j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032319128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo962068w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035625114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo962068w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035625114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200504313", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036657036"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39920001124", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037496035"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tetlet.2006.05.024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038678871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(97)00980-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039167155"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b901974j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041554900"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0dt00457j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042189947"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0dt00457j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042189947"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tet.2008.05.078", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044310345"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1521-3765(19980310)4:3<406::aid-chem406>3.0.co;2-#", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045548743"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.19960020617", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046687019"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048417113"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4039(00)94050-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052386057"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00040a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053860876"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00080a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053914313"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar950200t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055152073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar950200t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055152073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm00016a002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055406303"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00395a091", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055729091"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00433a027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055732125"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00998a052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055759975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01479a015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055800558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja048096a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055837578"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja048096a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055837578"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja063127i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055842368"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja063127i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055842368"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la8026682", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056163573"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la8026682", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056163573"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol006137b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056240706"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol006137b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056240706"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol101543x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056250285"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol101543x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056250285"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1055/s-0028-1088159", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057107842"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.77.179", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064477314"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2011-12", 
    "datePublishedReg": "2011-12-01", 
    "description": "Three new copper(I)-assembled [2]rotaxanes incorporating the same macrocycle and different axes containing a bipy, a phen or a terpy have been synthesized thanks to CuAAC reaction for attaching the stoppers. The influence of the nature of the base used for the stoppering reaction was investigated on the formation of the bipy-containing rotaxane. The yield of the [2]rotaxane synthesis was increased when using a phen as a coordinating unit in the thread with [Cu(CH3CN)4](PF6) as catalyst. The strong influence of the nature of the catalyst was clearly evidenced for the formation of the terpy rotaxane, increasing the yield of the stoppering reaction from 0 to 95% by just substituting the Cu(I) catalyst. Finally, the best conditions found for our systems are the use of Na2CO3 as a base and Cu(tren\u2032)Br as a catalyst.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10847-011-9986-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1119385", 
        "issn": [
          "1388-3127", 
          "2212-1765"
        ], 
        "name": "Journal of Inclusion Phenomena and Macrocyclic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3-4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "71"
      }
    ], 
    "name": "Formation of copper(I)-templated [2]rotaxanes using \u201cclick\u201d methodology: influence of the base, the thread and the catalyst", 
    "pagination": "507-515", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "73e2f4a2131d705cac360ab478485ea9bc85a56e426af853a3523acd99e61dbb"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10847-011-9986-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1024325005"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10847-011-9986-6", 
      "https://app.dimensions.ai/details/publication/pub.1024325005"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T16:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000488.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s10847-011-9986-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10847-011-9986-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10847-011-9986-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10847-011-9986-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10847-011-9986-6'


 

This table displays all metadata directly associated to this object as RDF triples.

216 TRIPLES      21 PREDICATES      67 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10847-011-9986-6 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N0d49cbe1ffb44abc91f56ef27939f6fc
4 schema:citation https://doi.org/10.1002/(sici)1521-3765(19980310)4:3<406::aid-chem406>3.0.co;2-#
5 https://doi.org/10.1002/1521-3773(20001002)39:19<3348::aid-anie3348>3.0.co;2-x
6 https://doi.org/10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0
7 https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4
8 https://doi.org/10.1002/anie.200504313
9 https://doi.org/10.1002/chem.19960020617
10 https://doi.org/10.1002/chem.200800480
11 https://doi.org/10.1002/chem.200902649
12 https://doi.org/10.1002/chem.201002220
13 https://doi.org/10.1016/j.inoche.2010.01.019
14 https://doi.org/10.1016/j.tet.2008.05.078
15 https://doi.org/10.1016/j.tetlet.2006.05.024
16 https://doi.org/10.1016/s0040-4020(97)00980-0
17 https://doi.org/10.1016/s0040-4039(00)94050-4
18 https://doi.org/10.1021/ar000174l
19 https://doi.org/10.1021/ar950200t
20 https://doi.org/10.1021/cm00016a002
21 https://doi.org/10.1021/cr00040a005
22 https://doi.org/10.1021/cr00080a007
23 https://doi.org/10.1021/ja0018264
24 https://doi.org/10.1021/ja00395a091
25 https://doi.org/10.1021/ja00433a027
26 https://doi.org/10.1021/ja00998a052
27 https://doi.org/10.1021/ja01479a015
28 https://doi.org/10.1021/ja048096a
29 https://doi.org/10.1021/ja056903f
30 https://doi.org/10.1021/ja063127i
31 https://doi.org/10.1021/jo011148j
32 https://doi.org/10.1021/jo962068w
33 https://doi.org/10.1021/la8026682
34 https://doi.org/10.1021/ol006137b
35 https://doi.org/10.1021/ol101543x
36 https://doi.org/10.1039/b901974j
37 https://doi.org/10.1039/b9nj00278b
38 https://doi.org/10.1039/c0dt00457j
39 https://doi.org/10.1039/c1nj20213h
40 https://doi.org/10.1039/c39920001124
41 https://doi.org/10.1055/s-0028-1088159
42 https://doi.org/10.1246/bcsj.77.179
43 https://doi.org/10.1246/bcsj.80.1856
44 schema:datePublished 2011-12
45 schema:datePublishedReg 2011-12-01
46 schema:description Three new copper(I)-assembled [2]rotaxanes incorporating the same macrocycle and different axes containing a bipy, a phen or a terpy have been synthesized thanks to CuAAC reaction for attaching the stoppers. The influence of the nature of the base used for the stoppering reaction was investigated on the formation of the bipy-containing rotaxane. The yield of the [2]rotaxane synthesis was increased when using a phen as a coordinating unit in the thread with [Cu(CH3CN)4](PF6) as catalyst. The strong influence of the nature of the catalyst was clearly evidenced for the formation of the terpy rotaxane, increasing the yield of the stoppering reaction from 0 to 95% by just substituting the Cu(I) catalyst. Finally, the best conditions found for our systems are the use of Na2CO3 as a base and Cu(tren′)Br as a catalyst.
47 schema:genre research_article
48 schema:inLanguage en
49 schema:isAccessibleForFree false
50 schema:isPartOf N89b6d9198a584c3f81ea737a49bae14e
51 Nce266fbe085c4e46ae1e2185a71bdf99
52 sg:journal.1119385
53 schema:name Formation of copper(I)-templated [2]rotaxanes using “click” methodology: influence of the base, the thread and the catalyst
54 schema:pagination 507-515
55 schema:productId N7419977135a04a5f988514d6452709d4
56 Na9a9c15c1372491db8b47a712237398e
57 Nfc61ad8b3de746d8a5a4f7f9133b4498
58 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024325005
59 https://doi.org/10.1007/s10847-011-9986-6
60 schema:sdDatePublished 2019-04-10T16:36
61 schema:sdLicense https://scigraph.springernature.com/explorer/license/
62 schema:sdPublisher N1fcf984f6d3c40d2a97d02a050dafe50
63 schema:url http://link.springer.com/10.1007/s10847-011-9986-6
64 sgo:license sg:explorer/license/
65 sgo:sdDataset articles
66 rdf:type schema:ScholarlyArticle
67 N0d49cbe1ffb44abc91f56ef27939f6fc rdf:first sg:person.0635260774.96
68 rdf:rest N22d808d5909449df9a83b68de41cc2d1
69 N1fcf984f6d3c40d2a97d02a050dafe50 schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 N22d808d5909449df9a83b68de41cc2d1 rdf:first sg:person.0672270631.42
72 rdf:rest Nb66895e6592241df95742e9e87d45169
73 N587ef49e86f04f1aa4b687db01aff2dd rdf:first sg:person.01025725303.67
74 rdf:rest Na0daa2b264bb4290a915b30441bd3d92
75 N5c24e64e895f403db03fa5cae74d1b2d rdf:first sg:person.0642450561.60
76 rdf:rest N587ef49e86f04f1aa4b687db01aff2dd
77 N7419977135a04a5f988514d6452709d4 schema:name readcube_id
78 schema:value 73e2f4a2131d705cac360ab478485ea9bc85a56e426af853a3523acd99e61dbb
79 rdf:type schema:PropertyValue
80 N89b6d9198a584c3f81ea737a49bae14e schema:volumeNumber 71
81 rdf:type schema:PublicationVolume
82 Na0daa2b264bb4290a915b30441bd3d92 rdf:first sg:person.0710563761.29
83 rdf:rest rdf:nil
84 Na9a9c15c1372491db8b47a712237398e schema:name dimensions_id
85 schema:value pub.1024325005
86 rdf:type schema:PropertyValue
87 Nb66895e6592241df95742e9e87d45169 rdf:first sg:person.01362476351.48
88 rdf:rest N5c24e64e895f403db03fa5cae74d1b2d
89 Nce266fbe085c4e46ae1e2185a71bdf99 schema:issueNumber 3-4
90 rdf:type schema:PublicationIssue
91 Nfc61ad8b3de746d8a5a4f7f9133b4498 schema:name doi
92 schema:value 10.1007/s10847-011-9986-6
93 rdf:type schema:PropertyValue
94 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
95 schema:name Chemical Sciences
96 rdf:type schema:DefinedTerm
97 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
98 schema:name Physical Chemistry (incl. Structural)
99 rdf:type schema:DefinedTerm
100 sg:journal.1119385 schema:issn 1388-3127
101 2212-1765
102 schema:name Journal of Inclusion Phenomena and Macrocyclic Chemistry
103 rdf:type schema:Periodical
104 sg:person.01025725303.67 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
105 schema:familyName Sauvage
106 schema:givenName Jean-Pierre
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025725303.67
108 rdf:type schema:Person
109 sg:person.01362476351.48 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
110 schema:familyName Heitz
111 schema:givenName Valérie
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01362476351.48
113 rdf:type schema:Person
114 sg:person.0635260774.96 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
115 schema:familyName Durola
116 schema:givenName Fabien
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0635260774.96
118 rdf:type schema:Person
119 sg:person.0642450561.60 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
120 schema:familyName Joosten
121 schema:givenName Antoine
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642450561.60
123 rdf:type schema:Person
124 sg:person.0672270631.42 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
125 schema:familyName Durot
126 schema:givenName Stéphanie
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0672270631.42
128 rdf:type schema:Person
129 sg:person.0710563761.29 schema:affiliation https://www.grid.ac/institutes/grid.462043.7
130 schema:familyName Trolez
131 schema:givenName Yann
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0710563761.29
133 rdf:type schema:Person
134 https://doi.org/10.1002/(sici)1521-3765(19980310)4:3<406::aid-chem406>3.0.co;2-# schema:sameAs https://app.dimensions.ai/details/publication/pub.1045548743
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1002/1521-3773(20001002)39:19<3348::aid-anie3348>3.0.co;2-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1001814930
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1002/1521-3773(20001002)39:19<3456::aid-anie3456>3.0.co;2-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048417113
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028820752
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1002/anie.200504313 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036657036
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1002/chem.19960020617 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046687019
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1002/chem.200800480 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003547937
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1002/chem.200902649 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024949533
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1002/chem.201002220 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011330717
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1016/j.inoche.2010.01.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017122903
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/j.tet.2008.05.078 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044310345
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/j.tetlet.2006.05.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038678871
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/s0040-4020(97)00980-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039167155
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/s0040-4039(00)94050-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052386057
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1021/ar000174l schema:sameAs https://app.dimensions.ai/details/publication/pub.1016430619
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1021/ar950200t schema:sameAs https://app.dimensions.ai/details/publication/pub.1055152073
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1021/cm00016a002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055406303
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1021/cr00040a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053860876
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1021/cr00080a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053914313
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1021/ja0018264 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007365527
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1021/ja00395a091 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055729091
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1021/ja00433a027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055732125
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1021/ja00998a052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055759975
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1021/ja01479a015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055800558
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1021/ja048096a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055837578
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1021/ja056903f schema:sameAs https://app.dimensions.ai/details/publication/pub.1020434230
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1021/ja063127i schema:sameAs https://app.dimensions.ai/details/publication/pub.1055842368
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1021/jo011148j schema:sameAs https://app.dimensions.ai/details/publication/pub.1032319128
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1021/jo962068w schema:sameAs https://app.dimensions.ai/details/publication/pub.1035625114
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1021/la8026682 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056163573
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1021/ol006137b schema:sameAs https://app.dimensions.ai/details/publication/pub.1056240706
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1021/ol101543x schema:sameAs https://app.dimensions.ai/details/publication/pub.1056250285
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1039/b901974j schema:sameAs https://app.dimensions.ai/details/publication/pub.1041554900
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1039/b9nj00278b schema:sameAs https://app.dimensions.ai/details/publication/pub.1019633258
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1039/c0dt00457j schema:sameAs https://app.dimensions.ai/details/publication/pub.1042189947
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1039/c1nj20213h schema:sameAs https://app.dimensions.ai/details/publication/pub.1015321352
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1039/c39920001124 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037496035
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1055/s-0028-1088159 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057107842
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1246/bcsj.77.179 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064477314
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1246/bcsj.80.1856 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010089936
213 rdf:type schema:CreativeWork
214 https://www.grid.ac/institutes/grid.462043.7 schema:alternateName Institut de Chimie de Strasbourg
215 schema:name Laboratoire de Chimie Organo-Minérale, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Université de Strasbourg, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France
216 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...