Phthalocyanine-based fluorescent chemosensor for the sensing of Zn (II) in dimethyl sulfoxide-acetonitrile View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-07-23

AUTHORS

Yasemin Çağlar, Nurhan Gümrükçüoğlu, Ece Tuğba Saka, Miraç Ocak, Halit Kantekin, Ümmühan Ocak

ABSTRACT

A tetra-substituted phthalocyanine based on 4-[2-(4-nitrophenoxy)ethoxy]phthalonitrile carrying nitrophenyl group for the sensing of Zn2+ has been prepared and characterized by elemental analysis, FT-IR, 1H and 13C NMR, and MS spectral data. The sensing of Zn2+ is based on the fluorescence quenching of Pc. Both absorbance and fluorescence spectra of ZnPc exhibit distinct changes in visible region in response to treatment with Zn2+ ion in dimethyl sulfoxide. The fluorescence spectrum of the ligand showed quenching in the intensity of the signal at 688 nm for Zn2+. The complex composition of ZnPc was found 1:1 by means of spectrophotometric and spectrofluorimetric titration data. The spectrofluorimetric method showed good sensitivity for Zn2+ with linear range and detection limit of 4.0 × 10−6–4.4 × 10−5 and 2.4×10−7 M, respectively. More... »

PAGES

443-447

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10847-011-0012-9

DOI

http://dx.doi.org/10.1007/s10847-011-0012-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029743807


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