Spectral Characteristics of Natural Cinnamic Acids Adsorbed on Aluminum Oxide Surface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2021-07-20

AUTHORS

N. T. Kartel, V. N. Barvinchenko, N. A. Lipkovska

ABSTRACT

The spectral characteristics (absorption band intensity and position) of structurally similar natural cinnamic acids absorbed on an aluminum oxide surface were found to depend on the surface concentration and aqueous solution pH. The conditional molar absorption coeffi cients [g/(mol∙cm)] of adsorbed cinnamic ε274nmS=1766,\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \left({\upvarepsilon}_{274 nm}^S=1766\right), $$\end{document} coumaric ε286nmS=2056,\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \left({\upvarepsilon}_{286 nm}^S=2056\right), $$\end{document} ferulic ε290nmS=1139,\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \left({\upvarepsilon}_{290 nm}^S=1139\right), $$\end{document} and caffeic acids ε350nmS=1163\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \left(\left({\upvarepsilon}_{350 nm}^S=1163\right.\right) $$\end{document} were determined. The optical densities of the adsorbed cinnamic acids were found to correlate with their concentrations in the initial solutions being analyzed. Owing to this, highly disperse aluminum oxide could be recommended as a solid-phase reagent for evaluation of cinnamic, coumaric, ferulic, and caffeic acids in plant-derived products using spectrophotometric or visual test methods. The possibility of selective determination of caffeic acid was also shown. More... »

PAGES

565-570

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-021-01210-7

DOI

http://dx.doi.org/10.1007/s10812-021-01210-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1139801523


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