Electron Paramagnetic Resonance of Mn2+ Ions in Nanosized Zinc Sulfide with a Planar Lattice Fault View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03

AUTHORS

I. P. Vorona, S. S. Ishchenko, V. G. Grachev, N. P. Baran, S. M. Okulov, V. V. Nosenko, A. V. Selishchev

ABSTRACT

We have studied the EPR of Mn2+ ions in three samples of cubic nano-ZnS made by different technologies and having different nanoparticle sizes. Manganese occurs in the samples as an uncontrolled impurity. The EPR spectra can be described by two components: the spectrum of the Mn2+ in a cubic environment (Mn2+(C)) with parameters g = 2.0022 ± 0.0002, A = (–63.5 ± 0.5)·10–4 cm–1, 0 b4 ≥ 3.5·10–4 cm–1; and the spectrum of the Mn2+ ion associated with a planar lattice stacking fault (Mn2+ (F)), with parameters g = 2.0022 ± 0.0002, A = (–63.5 ± 0.5)·10–4 cm–1, b20\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {b}_2^0 $$\end{document} = (–36 ± 1)·10–4 cm–1. The ratio of the number of centers Mn2+(C)/Mn2+(F) is 2.1:1 for sample 1 and 1.7:1 for samples 2 and 3. Planar stacking faults are typical lattice faults for cubic nano-ZnS. EPR of the Mn2+ ions lets us monitor the presence of these ions. More... »

PAGES

130-133

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-019-00792-7

DOI

http://dx.doi.org/10.1007/s10812-019-00792-7

DIMENSIONS

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