Ontology type: schema:ScholarlyArticle
2018-03
AUTHORSI. I. Shafranyosh, I. E. Mitropolskiy, V. V. Kuzma, Yu. Yu. Svyda, M. I. Sukhoviya
ABSTRACTPhotoelectron spectroscopy was applied to pyrimidine nitrogenous bases, an important class of six-membered heterocyclic compounds incorporated into nucleic acids. The emission spectrum of uracil adsorbed on a ceramic surface that was obtained by bombardment with 600-eV electrons in a high vacuum was analyzed. Broad bands with maxima at 335, 435, and 495 nm were observed in the UV and visible regions. The strongest band (λ = 335 nm) was attributed to fluorescence and corresponded to a singlet–singlet transition from the first excited electronic state into the molecular ground state. Electronic transitions from a triplet T1 into the ground state formed a weaker phosphorescence band (λ = 435 nm). The nature of the band maximum at 495 nm is discussed. The obtained luminescence spectrum was compared with photoluminescence spectra in various phases. More... »
PAGES32-36
http://scigraph.springernature.com/pub.10.1007/s10812-018-0607-7
DOIhttp://dx.doi.org/10.1007/s10812-018-0607-7
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