Effect of Intramolecular Rotation on Collisional Luminescence Depolarization of Polyatomic Molecules View Full Text


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Article Info

DATE

2015-01

AUTHORS

A. P. Blokhin, V. A. Tolkachev

ABSTRACT

A model for collisional luminescence depolarization of molecular complexes with internal rotation at an arbitrary ratio of moments of inertia of the moving parts was developed. Theoretical expressions for the luminescence anisotropy in the J-diffusion model and generalizations of the Levshin–Perrin relations were obtained. It was shown that the luminescence depolarization of the complexes depended strongly on the ratio of the moments of inertia of the complex parts, the orientation of the rotation axes, and the directions of the transition moments. More... »

PAGES

930-937

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-015-0031-1

DOI

http://dx.doi.org/10.1007/s10812-015-0031-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005867134


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