Anisotropy of Dual Fluorescence of 2,3-Diazabicyclo[2.2.2]Oct-2-Ene and 1,4-Dimethyl-(2,3-Diazabicyclo[2.2.2]Oct-2-Ene) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

A. P. Lugovskii, V. A. Povedailo, D. L. Yakovlev

ABSTRACT

Absorption, fluorescence excitation, and fluorescence spectra and the fluorescence polarization as a function of emission wavelength were measured at 77 K for glassy EtOH solutions of 2,3-diazabicyclo[2.2.2]oct-2-ene and 1,4-dimethyl-(2,3-diazabicyclo[2.2.2]oct-2-ene). It was concluded from an analysis of the results that two excited electronic states were responsible for the emission of these compounds. The transition dipole moment vectors from the ground state into the excited ones were mutually perpendicular so that the corresponding spectra were shifted. More... »

PAGES

377-380

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-014-9940-7

DOI

http://dx.doi.org/10.1007/s10812-014-9940-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043446421


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