Effect of molecular structure nonrigidity on anisotropy of dipole absorption cross section View Full Text


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Article Info

DATE

2011-01

AUTHORS

V. A. Tolkachev, A. P. Blokhin

ABSTRACT

The influence of the nonrigidity of free complex asymmetric top molecules on the anisotropy of the absorption cross section over various rotational configurations has been studied under conditions where the total angular momentum is conserved. It is shown that the nonrigidity-induced cross section anisotropy is maximal for the optical transition with the dipole moment collinear to the axis of the molecule’s mean moment of inertia and rapidly decreases with the rise of the intramolecular flexibility. For all types of tops, disturbances from internal motions are stronger in the region where the principal axes of inertia are collinear with the total rotational angular momentum. More... »

PAGES

778-783

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-011-9402-4

DOI

http://dx.doi.org/10.1007/s10812-011-9402-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022359882


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