Anomalies in oxygen-induced quenching of electronically excited states of 4,4′-bis[2-(1,3)-benzoxazol-2-yl)ethenyl]biphenyl in the vapor phase View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-11

AUTHORS

E. V. Dudko, I. I. Kalosha, A. V. Kukhto, I. N. Kukhto, V. A. Tolkachev, V. K. Ol’khovik, D. A. Vasilevskii

ABSTRACT

From oxygen-induced quenching of polarized fluorescence of 4,4′-bis[2-(1,3-benzoxazol-2-yl)ethenyl]biphenyl, we have observed structural transformation in electronically excited molecules with retention of fluorescent capability, initiated by collisions with oxygen. Replacing two hydrogen atoms with fluorine in the ortho positions of the diphenyl moiety of the molecule leads to absence of quenching upon collisions with oxygen molecules, owing to the electronegative properties of fluorine atoms. More... »

PAGES

898-901

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-009-9114-1

DOI

http://dx.doi.org/10.1007/s10812-009-9114-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039189236


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