Mechanism for quenching of the luminescence of 9,10-anthraquinone vapor by oxygen View Full Text


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Article Info

DATE

2008-01

AUTHORS

E. V. Dudko, I. I. Kalosha, V. A. Tolkachev

ABSTRACT

The fluorescence of 9,10-anthraquinone, 1-aminoanthraquinone, 1,4-diaminoanthraquinone, and 1,5-diaminoanthraquinone is not quenched by oxygen because the singlet-triplet energy difference in these compounds is less than the energy needed for excitation of the triplet state of oxygen to the singlet state. Luminescence of 9,10-anthraquinone is quenched because it is mainly phosphorescence, for which the singlet-triplet difference is sufficient for quenching by a mechanism involving singlet oxygen formation. The weak fluorescence of 9,10-anthraquinone is not quenched. The resistance of the fluorescence of 9,10-anthraquinone vapor to quenching by oxygen and the quenching of its phosphorescence explain the different effects of oxygen on the luminescence of α-substituted and β-substituted anthraquinones known from the literature, and indicate that their singlet excited state cannot convert triplet oxygen to singlet oxygen. More... »

PAGES

80-85

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-008-9010-0

DOI

http://dx.doi.org/10.1007/s10812-008-9010-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043195752


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