Singlet-Singlet Electronic Excitation Energy Transfer in a Bichromophore Cooled in a Supersonic Jet View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-07

AUTHORS

V. A. Povedailo, D. L. Yakovlev

ABSTRACT

The fluorescence excitation spectra and polarization of the fluorescence of a bichromophore cooled in a supersonic jet are measured. The bichromophore consists of 2,5-diphenyloxazole (PPO) and 1-(5′-phenyl-1′, 3′-oxazole-2′-yl)-4-(5′-phenyl-1′,3′,4′-oxadiazole-2′-yl)-benzene (POPDP) connected by the methylene bridge -(CH2)-. Based on the analysis of these components and theoretical calculations, it has been proven that the total intramolecular singlet-singlet transfer of the energy of electronic excitation from the energy donor PPO to the acceptor POPDP occurs in a time of 10−12 sec. More... »

PAGES

495-498

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10812-005-0103-8

DOI

http://dx.doi.org/10.1007/s10812-005-0103-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032425039


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