Optimization of synthesis condition of water-resistant and thin titanium oxide layer-coated Ni-rich layered cathode materials and their cathode performance View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-01

AUTHORS

Yubin Liu, Toyokazu Tanabe, Yuta Irii, Fumihiko Maki, Takashi Tsuda, Takao Gunji, Shinsaku Ugawa, Yuta Asai, Hojin Lee, Takeo Ohsaka, Futoshi Matsumoto

ABSTRACT

In this study, in order to develop water-resistant LiNiaCobAl1−a−bO2 (a > 0.85, NCA) cathode materials which exhibit high-rate performance, the surface coating of NCA with titanium oxide (TiOx) was examined. The synthesis conditions for the TiOx-coated NCA cathode materials were investigated, by taking into account some essential factors in the surface coating of NCA by TiOx, with a view to improving the rate performance. We successfully prepared the TiOx-coated NCA cathode material, the rate performance of which is superior to that of the conventionally prepared NCA cathode materials, typically using a polyvinylidene difluoride (PVdF) binder and N-methyl-2-pyrrolidone (NMP) solvent. Their surface analysis suggested that the specific surface structure of TiOx layer coated on the NCA particle leads to both a water-resistant property and a high permeability of Li+ ions through it in the charging/discharging process. More... »

PAGES

1-12

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10800-018-1272-5

DOI

http://dx.doi.org/10.1007/s10800-018-1272-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110126200


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