EIS investigation of the deposition of trivalent chromium coatings on Al 6063 alloy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

Hui Cheng Yu, Bai Zhen Chen, Xi Chang Shi, Hai Ying Wu, Bin Li

ABSTRACT

The influence of five variables (i.e. deposition temperature, time, bath pH, and concentrations of Cr3+ compound (KCr(SO4)2) and H3PO4) on the preparation of Cr3+ coating on Al 6063 alloy was investigated using AC impedance spectroscopy (EIS) in 3.5 wt% NaCl. The optimal conditions were determined by AC impedance spectroscopy. The results indicated that the formation and quality of the coating were very sensitive to the deposition bath pH. A mechanism was proposed to explain the results. A simple model was derived and experimentally tested in terms of an equivalent circuit. Good agreement was found between the model predictions and the experimental results. The morphologies of the coated and uncoated electrodes were examined by scanning electron microscopy (SEM), and the results also support the proposed surface model. More... »

PAGES

303-309

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10800-008-9673-5

DOI

http://dx.doi.org/10.1007/s10800-008-9673-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019157903


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