Structure of Vanadium-Oxygen and Phosphorus-Oxygen Groups in Molten Alkali and Alkaline-Earth Vanadates and Phosphates: A High-Temperature Raman Scattering Study View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

Yu. K. Voron'ko, A. A. Sobol', V. E. Shukshin

ABSTRACT

The melting of alkali-metal ortho-, pyro-, and polyvanadates and V2O5 is investigated by high-temperature Raman scattering spectroscopy. The Raman lines arising from the characteristic vibrational modes of the terminal, middle, and bridging groups of anions with various degrees of condensation of vanadium-oxygen tetrahedra in vanadate melts are identified. The origin of structural similarities and distinctions between the vanadium-oxygen and phosphorus-oxygen complexes in melts is analyzed. More... »

PAGES

1097-1106

Journal

TITLE

Inorganic Materials

ISSUE

10

VOLUME

41

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10789-005-0267-x

DOI

http://dx.doi.org/10.1007/s10789-005-0267-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047438541


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