Mössbauer study of the effect of rare earth substitution into montmorillonite View Full Text


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Article Info

DATE

2016-12

AUTHORS

E. Kuzmann, L. H. Singh, V. K. Garg, A. C. de Oliveira, E. M. Kovács, Á. M. Molnár, Z. Homonnay, P. Kónya, N. M. Nagy, J. Kónya

ABSTRACT

Novel montmorillonites were prepared by the exchange of the interlayer cations with a series of rare earth cations (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, and Er) and characterized by XRD, XRF, SEM, chemical analysis and 57Fe Mössbauer spectroscopy. An unexpected magnetically split component, assigned to iron being in the interlayer space, was observed in the Mössbauer spectra at 78K in some rare earth cation exchanged montmorillonite. This paper is the initial report about this observation. The transition of iron from the octahedral site to the interlayer and possible incorporation of rare earths in sites different from those which are in the interlayer space was concluded. More... »

PAGES

2

References to SciGraph publications

  • 2005-11. Kinetics of strontium ion adsorption on natural clay samples in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1981-11. The use of mössbauer spectroscopy of iron in clay mineralogy in PHYSICS AND CHEMISTRY OF MINERALS
  • 2007-02. Incorporation of Fe in the interlayer of Na-bentonite via treatment with FeCl3 in acetone in CLAYS AND CLAY MINERALS
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    http://scigraph.springernature.com/pub.10.1007/s10751-016-1225-5

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    http://dx.doi.org/10.1007/s10751-016-1225-5

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