Influence of Mn-for-Fe substitution on structural properties of synthetic goethite View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

J. A. Mejía Gómez, V. G. de Resende, J. Antonissen, E. De Grave

ABSTRACT

In order to study the effect of alloying elements, such as manganese, on the properties of the rust on weathering steels, a series of Mn-goethite samples containing different amounts of Mn were synthesized from ferrihydrite in alkaline media. The samples were characterized by X-ray diffraction (XRD) and Mössbauer spectroscopy. The cell parameters calculated from the XRD patterns showed clearly that the a- and c-parameters decrease while the b-parameter increases with increasing Mn concentration, indicating that the octahedra of the goethite structure become distorted by an incorporation of Mn (Jahn–Teller-effect). Mössbauer spectra of the samples were recorded at room temperature (RT) and at 80 K. The quadrupole shift values gradually decrease with increasing Mn substitution in the goethite structure. It has been observed that the magnetic hyperfine field values of maximum probability are reduced with increasing Mn in the samples. No doublet component was observed in the RT MS spectra suggesting that no effects of superparamagnetim resulting from smaller particles are present. More... »

PAGES

143-149

Journal

TITLE

Hyperfine Interactions

ISSUE

1-3

VOLUME

189

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10751-009-9909-8

DOI

http://dx.doi.org/10.1007/s10751-009-9909-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003538738


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Ghent University", 
          "id": "https://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Department of Subatomic and Radiation Physics, University of Ghent, 9000, Ghent, Belgium", 
            "Arcelor Research Industry Gent (ARIG), 9060, Zelzate, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mej\u00eda G\u00f3mez", 
        "givenName": "J. A.", 
        "id": "sg:person.010411622337.98", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010411622337.98"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ghent University", 
          "id": "https://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Department of Subatomic and Radiation Physics, University of Ghent, 9000, Ghent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "de Resende", 
        "givenName": "V. G.", 
        "id": "sg:person.016243135551.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016243135551.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Arcelor Research Industry Gent (ARIG), 9060, Zelzate, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antonissen", 
        "givenName": "J.", 
        "id": "sg:person.016472614253.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016472614253.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ghent University", 
          "id": "https://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Department of Subatomic and Radiation Physics, University of Ghent, 9000, Ghent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "De Grave", 
        "givenName": "E.", 
        "id": "sg:person.014440363007.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014440363007.52"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:hype.0000003778.31809.63", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001118220", 
          "https://doi.org/10.1023/b:hype.0000003778.31809.63"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1021247828279", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002131147", 
          "https://doi.org/10.1023/a:1021247828279"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02400487", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010680469", 
          "https://doi.org/10.1007/bf02400487"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02400487", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010680469", 
          "https://doi.org/10.1007/bf02400487"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.corsci.2004.10.018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014177404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemgeo.2004.11.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018307633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(84)90107-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035946975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(84)90107-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035946975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02074257", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038614452", 
          "https://doi.org/10.1007/bf02074257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02074257", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038614452", 
          "https://doi.org/10.1007/bf02074257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/claymin.1984.019.4.02", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064113020"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/claymin.1990.025.4.09", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064113382"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1017/cbo9780511524899", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1098667649"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-02", 
    "datePublishedReg": "2009-02-01", 
    "description": "In order to study the effect of alloying elements, such as manganese, on the properties of the rust on weathering steels, a series of Mn-goethite samples containing different amounts of Mn were synthesized from ferrihydrite in alkaline media. The samples were characterized by X-ray diffraction (XRD) and M\u00f6ssbauer spectroscopy. The cell parameters calculated from the XRD patterns showed clearly that the a- and c-parameters decrease while the b-parameter increases with increasing Mn concentration, indicating that the octahedra of the goethite structure become distorted by an incorporation of Mn (Jahn\u2013Teller-effect). M\u00f6ssbauer spectra of the samples were recorded at room temperature (RT) and at 80 K. The quadrupole shift values gradually decrease with increasing Mn substitution in the goethite structure. It has been observed that the magnetic hyperfine field values of maximum probability are reduced with increasing Mn in the samples. No doublet component was observed in the RT MS spectra suggesting that no effects of superparamagnetim resulting from smaller particles are present.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10751-009-9909-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1038685", 
        "issn": [
          "0304-3843", 
          "1572-9540"
        ], 
        "name": "Hyperfine Interactions", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "189"
      }
    ], 
    "name": "Influence of Mn-for-Fe substitution on structural properties of synthetic goethite", 
    "pagination": "143-149", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "10db69f56b3cd77aa364b3479100c9845fd0e0ba38d1815950fad8f185b78826"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10751-009-9909-8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1003538738"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10751-009-9909-8", 
      "https://app.dimensions.ai/details/publication/pub.1003538738"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:09", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000338_0000000338/records_47967_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10751-009-9909-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10751-009-9909-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10751-009-9909-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10751-009-9909-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10751-009-9909-8'


 

This table displays all metadata directly associated to this object as RDF triples.

119 TRIPLES      21 PREDICATES      37 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10751-009-9909-8 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N96a4f0c0478544408ebf376bc75e2057
4 schema:citation sg:pub.10.1007/bf02074257
5 sg:pub.10.1007/bf02400487
6 sg:pub.10.1023/a:1021247828279
7 sg:pub.10.1023/b:hype.0000003778.31809.63
8 https://doi.org/10.1016/0304-8853(84)90107-0
9 https://doi.org/10.1016/j.chemgeo.2004.11.004
10 https://doi.org/10.1016/j.corsci.2004.10.018
11 https://doi.org/10.1017/cbo9780511524899
12 https://doi.org/10.1180/claymin.1984.019.4.02
13 https://doi.org/10.1180/claymin.1990.025.4.09
14 schema:datePublished 2009-02
15 schema:datePublishedReg 2009-02-01
16 schema:description In order to study the effect of alloying elements, such as manganese, on the properties of the rust on weathering steels, a series of Mn-goethite samples containing different amounts of Mn were synthesized from ferrihydrite in alkaline media. The samples were characterized by X-ray diffraction (XRD) and Mössbauer spectroscopy. The cell parameters calculated from the XRD patterns showed clearly that the a- and c-parameters decrease while the b-parameter increases with increasing Mn concentration, indicating that the octahedra of the goethite structure become distorted by an incorporation of Mn (Jahn–Teller-effect). Mössbauer spectra of the samples were recorded at room temperature (RT) and at 80 K. The quadrupole shift values gradually decrease with increasing Mn substitution in the goethite structure. It has been observed that the magnetic hyperfine field values of maximum probability are reduced with increasing Mn in the samples. No doublet component was observed in the RT MS spectra suggesting that no effects of superparamagnetim resulting from smaller particles are present.
17 schema:genre research_article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf N36eb567beabf40b390f9a95685ac44d7
21 N3c008e78711749008aec4c20dcccf311
22 sg:journal.1038685
23 schema:name Influence of Mn-for-Fe substitution on structural properties of synthetic goethite
24 schema:pagination 143-149
25 schema:productId N0aa1f04d1621412f83c8472cd403d35e
26 N72880d91f47142a1b68bf9bcaa1946ca
27 N9ecf17b9cda346beb4efc6834ba24a5f
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003538738
29 https://doi.org/10.1007/s10751-009-9909-8
30 schema:sdDatePublished 2019-04-11T09:09
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher Nf3b7359a42064652b4178760c0e6b4bd
33 schema:url http://link.springer.com/10.1007%2Fs10751-009-9909-8
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N0aa1f04d1621412f83c8472cd403d35e schema:name doi
38 schema:value 10.1007/s10751-009-9909-8
39 rdf:type schema:PropertyValue
40 N2c7e13db70b448578c3e0f1da7508df8 rdf:first sg:person.014440363007.52
41 rdf:rest rdf:nil
42 N36eb567beabf40b390f9a95685ac44d7 schema:volumeNumber 189
43 rdf:type schema:PublicationVolume
44 N3c008e78711749008aec4c20dcccf311 schema:issueNumber 1-3
45 rdf:type schema:PublicationIssue
46 N72880d91f47142a1b68bf9bcaa1946ca schema:name dimensions_id
47 schema:value pub.1003538738
48 rdf:type schema:PropertyValue
49 N8d26cb41b7c248189c1326719982f941 rdf:first sg:person.016472614253.40
50 rdf:rest N2c7e13db70b448578c3e0f1da7508df8
51 N96a4f0c0478544408ebf376bc75e2057 rdf:first sg:person.010411622337.98
52 rdf:rest Nf6c9b05da46341a2b013ba1088edb77c
53 N9ecf17b9cda346beb4efc6834ba24a5f schema:name readcube_id
54 schema:value 10db69f56b3cd77aa364b3479100c9845fd0e0ba38d1815950fad8f185b78826
55 rdf:type schema:PropertyValue
56 Nee55d2c00c59479d957e127e16160522 schema:name Arcelor Research Industry Gent (ARIG), 9060, Zelzate, Belgium
57 rdf:type schema:Organization
58 Nf3b7359a42064652b4178760c0e6b4bd schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 Nf6c9b05da46341a2b013ba1088edb77c rdf:first sg:person.016243135551.79
61 rdf:rest N8d26cb41b7c248189c1326719982f941
62 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
63 schema:name Chemical Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
66 schema:name Physical Chemistry (incl. Structural)
67 rdf:type schema:DefinedTerm
68 sg:journal.1038685 schema:issn 0304-3843
69 1572-9540
70 schema:name Hyperfine Interactions
71 rdf:type schema:Periodical
72 sg:person.010411622337.98 schema:affiliation https://www.grid.ac/institutes/grid.5342.0
73 schema:familyName Mejía Gómez
74 schema:givenName J. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010411622337.98
76 rdf:type schema:Person
77 sg:person.014440363007.52 schema:affiliation https://www.grid.ac/institutes/grid.5342.0
78 schema:familyName De Grave
79 schema:givenName E.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014440363007.52
81 rdf:type schema:Person
82 sg:person.016243135551.79 schema:affiliation https://www.grid.ac/institutes/grid.5342.0
83 schema:familyName de Resende
84 schema:givenName V. G.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016243135551.79
86 rdf:type schema:Person
87 sg:person.016472614253.40 schema:affiliation Nee55d2c00c59479d957e127e16160522
88 schema:familyName Antonissen
89 schema:givenName J.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016472614253.40
91 rdf:type schema:Person
92 sg:pub.10.1007/bf02074257 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038614452
93 https://doi.org/10.1007/bf02074257
94 rdf:type schema:CreativeWork
95 sg:pub.10.1007/bf02400487 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010680469
96 https://doi.org/10.1007/bf02400487
97 rdf:type schema:CreativeWork
98 sg:pub.10.1023/a:1021247828279 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002131147
99 https://doi.org/10.1023/a:1021247828279
100 rdf:type schema:CreativeWork
101 sg:pub.10.1023/b:hype.0000003778.31809.63 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001118220
102 https://doi.org/10.1023/b:hype.0000003778.31809.63
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1016/0304-8853(84)90107-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035946975
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/j.chemgeo.2004.11.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018307633
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/j.corsci.2004.10.018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014177404
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1017/cbo9780511524899 schema:sameAs https://app.dimensions.ai/details/publication/pub.1098667649
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1180/claymin.1984.019.4.02 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064113020
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1180/claymin.1990.025.4.09 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064113382
115 rdf:type schema:CreativeWork
116 https://www.grid.ac/institutes/grid.5342.0 schema:alternateName Ghent University
117 schema:name Arcelor Research Industry Gent (ARIG), 9060, Zelzate, Belgium
118 Department of Subatomic and Radiation Physics, University of Ghent, 9000, Ghent, Belgium
119 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...