Opianic Acid in the Synthesis of Benzimidazole Derivatives View Full Text


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Article Info

DATE

2017-01

AUTHORS

G. S. Borodkin, L. Yu. Ukhin, L. V. Belousova, E. N. Shepelenko, A. V. Alekseenko

ABSTRACT

Heating an equimolar mixture of opianic acid and o-phenylenediamine in MeOH or EtOH produced 2-(2-carboxy-3,4-dimethoxyphenyl)benzimidazole, which was readily dehydrated in refluxing acetic or propionic anhydride to 11H-1,2-dimethoxyisoindolo[2,3-a]benzimidazol-11-one. Analogous reactions were carried out with 4,5-dichloro-o-phenylenediamine.

PAGES

118-120

References to SciGraph publications

  • 2007-10. “Blue” laccases in BIOCHEMISTRY (MOSCOW)
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10600-017-1923-5

    DOI

    http://dx.doi.org/10.1007/s10600-017-1923-5

    DIMENSIONS

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