Synthesis of a Triterpenoid with a 1,2,4,5-Tetraoxane Fragment View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-01

AUTHORS

E. Yu. Yamansarov, O. B. Kazakova, A. N. Lobov, D. V. Kazakov, K. Yu. Suponitskii

ABSTRACT

Acid-catalyzed formation of the peroxyacetal of cyclohexanone bis-hydroperoxide and a triterpene ketone synthesized for the first time 19β,28-epoxy-28-oxo-18α-olean-3-spiro-6′-(1′,2′,4′,5′-tetraoxacyclohexane)-3′-spirocyclohexane, the structure of which was confirmed by NMR spectroscopy and an x-ray crystal structure analysis. 19β,28-Epoxy-28-oxo-18α-olean-1-en-3-one was formed as a side product during oxidative dehydration of 28-oxoallobetulone.

PAGES

97-102

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-015-1211-1

DOI

http://dx.doi.org/10.1007/s10600-015-1211-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024101468


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