Synthesis of 8-amino- and 8-acetyl(benzoyl) aminomackinazolinones and their condensation with aldehydes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-05

AUTHORS

A. Sh. Abdurazakov, B. Zh. Elmuradov, I. S. Ortikov, M. G. Levkovich, Kh. M. Shakhidoyatov

ABSTRACT

Methods for preparing of 8-nitro- and 8-aminomackinazolinones were improved. 8-Acetyl(benzoyl)aminomackinazolinones reacted smoothly with aromatic aldehydes and furfurol in glacial acetic acid to give the corresponding 4-arylidene-substituted derivatives. Reaction of 8-aminomackinazolinone with aromatic aldehydes in glacial acetic acid was accompanied by acetylation of the amine and gave 8-acetylamino-4-arylidenemackinazolinones. Reaction of 8-aminomackinazolinone and p-nitrobenzaldehyde in propionic acid produced 8-[(4′ -nitrobenzylidene)amino]-4-(4″-nitrobenzylidene)mackinazolinone. In contrast, the reaction in Py occurred selectively at the amine to form the corresponding Schiff base 8-[(4′-nitrobenzylidene)amino]mackinazolinone. More... »

PAGES

305-310

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-013-0587-z

DOI

http://dx.doi.org/10.1007/s10600-013-0587-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044064168


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