Spectroscopic study of the reaction of a natural arabinogalactan polysaccharide with 3-hydroxyflavones in aqueous solutions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

N. N. Pogodaeva, S. A. Medvedeva, B. G. Sukhov, L. I. Larina

ABSTRACT

The reaction of an arabinogalactan polysaccharide with 3-hydroxyflavones (3-hydroxyflavone, 5-methoxy3-hydroxyflavone, quercetin) in aqueous solutions was studied for the first time using spectral methods (IR, UV, heteronuclear NMR). It was found that the arabinogalactan in aqueous solution formed molecular complexes with the diketo-forms of the 3-hydroxyflavones and increased their solubility in water, thereby exhibiting hydrotropic properties relative to these compounds. It was shown that the 3-hydroxyflavone diketo-forms formed because water weakened the intramolecular H-bonds that stabilized their enol forms. More... »

PAGES

723-727

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-012-0368-0

DOI

http://dx.doi.org/10.1007/s10600-012-0368-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030938991


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