Synthesis of hybrid molecules containing fragments of sesquiterpene lactones and plant alkaloids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-01

AUTHORS

A. V. Belovodskii, E. E. Shul’ts, M. M. Shakirov, V. E. Romanov, B. Zh. Elmuradov, Kh. M. Shakhidoyatov, G. A. Tolstikov

ABSTRACT

The Pd-catalyzed arylation of isoalantolactone by deoxyvasicinone and lappaconitine halides occurred with formation mainly of cross-coupling products with the (E)-configuration of the double bond. Another three compounds were isolated from the reaction of isoalantolactone with 6-bromodeoxyvasicinone. These were the lactone diarylation product, a compound with the (Z)-configuration of the double bond, and a product with a shift of the C(11,13) double bond and configuration inversion at C(8). The new compounds are interesting as potential biologically active agents. More... »

PAGES

880-885

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-011-9774-y

DOI

http://dx.doi.org/10.1007/s10600-011-9774-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007773854


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