Z-and E-conformers of N-chloroacetylcytisine View Full Text


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Article Info

DATE

2010-11

AUTHORS

T. F. Ibragimov, M. G. Levkovich, V. A. Saprykina, Kh. M. Shakhidoyatov

ABSTRACT

N-Chloroacetylcytisine was synthesized by acylation of (–)-cytisine. Stable Z- and E-conformers with respect to rotational isomerism around the N-12–CO bond were found in PMR spectra at room temperature. The point at which PMR resonances of the Z- and E-conformers coalesced upon heating was measured. The transition barrier between the conformers was estimated. More... »

PAGES

767-770

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-010-9736-9

DOI

http://dx.doi.org/10.1007/s10600-010-9736-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010015481


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