Directions of reactions of 6-amino-, -acetylamino-, and -benzoylaminodeoxyvasicinones with aldehydes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-05

AUTHORS

B. Zh. Elmuradov, A. Sh. Abdurazakov, Kh. M. Shakhidoyatov

ABSTRACT

6-Acetylamino- and -benzoylamino-9-arylidenedeoxyvasicinones were synthesized by reaction of 6-amino(3), -acetylamino- (4), and -benzoylamino- (5) -deoxyvasicinones (DOV) with aromatic aldehydes and furfurol in glacial acetic acid. It was shown that the amino group of 6-aminodeoxyvasicinone underwent acylation upon reaction with aldehydes to form 6-acetylamino-DOV, which reacted with aldehydes to form 9-arylidene derivatives. Carrying out this condensation in toluene, o-xylene, and ethanol produced a mixture of condensation products at the 6-amino-and a-CH2-groups. It was found that condensati on of 3 with 4-nitrobenzaldehyde in pyridine formed exclusively the Schiff bases. Methods for preparing 6-nitrodeoxyvasicinone and for its reduction were improved. More... »

PAGES

262-267

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-010-9583-8

DOI

http://dx.doi.org/10.1007/s10600-010-9583-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051493721


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Elmuradov", 
        "givenName": "B. Zh.", 
        "id": "sg:person.016612326652.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016612326652.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Abdurazakov", 
        "givenName": "A. Sh.", 
        "id": "sg:person.014233004507.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014233004507.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shakhidoyatov", 
        "givenName": "Kh. M.", 
        "id": "sg:person.015706066705.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2010-05", 
    "datePublishedReg": "2010-05-01", 
    "description": "6-Acetylamino- and -benzoylamino-9-arylidenedeoxyvasicinones were synthesized by reaction of 6-amino(3), -acetylamino- (4), and -benzoylamino- (5) -deoxyvasicinones (DOV) with aromatic aldehydes and furfurol in glacial acetic acid. It was shown that the amino group of 6-aminodeoxyvasicinone underwent acylation upon reaction with aldehydes to form 6-acetylamino-DOV, which reacted with aldehydes to form 9-arylidene derivatives. Carrying out this condensation in toluene, o-xylene, and ethanol produced a mixture of condensation products at the 6-amino-and a-CH2-groups. It was found that condensati on of 3 with 4-nitrobenzaldehyde in pyridine formed exclusively the Schiff bases. Methods for preparing 6-nitrodeoxyvasicinone and for its reduction were improved.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10600-010-9583-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1009660", 
        "issn": [
          "0009-3130", 
          "1573-8388"
        ], 
        "name": "Chemistry of Natural Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "name": "Directions of reactions of 6-amino-, -acetylamino-, and -benzoylaminodeoxyvasicinones with aldehydes", 
    "pagination": "262-267", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f54b4bf18369dcb52a7b61aa5d8db9a0ef3d18e8a83f05a3c961549f17d9d15e"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10600-010-9583-8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1051493721"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10600-010-9583-8", 
      "https://app.dimensions.ai/details/publication/pub.1051493721"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T20:48", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000516.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10600-010-9583-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9583-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9583-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9583-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9583-8'


 

This table displays all metadata directly associated to this object as RDF triples.

75 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10600-010-9583-8 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N813d48a95ddd495798261132801d5e8c
4 schema:datePublished 2010-05
5 schema:datePublishedReg 2010-05-01
6 schema:description 6-Acetylamino- and -benzoylamino-9-arylidenedeoxyvasicinones were synthesized by reaction of 6-amino(3), -acetylamino- (4), and -benzoylamino- (5) -deoxyvasicinones (DOV) with aromatic aldehydes and furfurol in glacial acetic acid. It was shown that the amino group of 6-aminodeoxyvasicinone underwent acylation upon reaction with aldehydes to form 6-acetylamino-DOV, which reacted with aldehydes to form 9-arylidene derivatives. Carrying out this condensation in toluene, o-xylene, and ethanol produced a mixture of condensation products at the 6-amino-and a-CH2-groups. It was found that condensati on of 3 with 4-nitrobenzaldehyde in pyridine formed exclusively the Schiff bases. Methods for preparing 6-nitrodeoxyvasicinone and for its reduction were improved.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf Naf63162255434098b7485decaadda9a4
11 Nb09f5896a4704ded89eaba674f702627
12 sg:journal.1009660
13 schema:name Directions of reactions of 6-amino-, -acetylamino-, and -benzoylaminodeoxyvasicinones with aldehydes
14 schema:pagination 262-267
15 schema:productId N65fe3c917ded4d9b8c1fca70c63533ff
16 Nbef28678c91b43c79859032dc95cbfe5
17 Nf4bd7c73d8b6411a957d9f1d2729cbcf
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051493721
19 https://doi.org/10.1007/s10600-010-9583-8
20 schema:sdDatePublished 2019-04-10T20:48
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Nc9b27a6ccdcf4716812ce88008afe751
23 schema:url http://link.springer.com/10.1007%2Fs10600-010-9583-8
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N65fe3c917ded4d9b8c1fca70c63533ff schema:name dimensions_id
28 schema:value pub.1051493721
29 rdf:type schema:PropertyValue
30 N695410da02894379b23ddb6fbbdf3061 rdf:first sg:person.014233004507.42
31 rdf:rest Nd5bcb07a65ac459998929719f32207d6
32 N813d48a95ddd495798261132801d5e8c rdf:first sg:person.016612326652.48
33 rdf:rest N695410da02894379b23ddb6fbbdf3061
34 Naf63162255434098b7485decaadda9a4 schema:volumeNumber 46
35 rdf:type schema:PublicationVolume
36 Nb09f5896a4704ded89eaba674f702627 schema:issueNumber 2
37 rdf:type schema:PublicationIssue
38 Nbef28678c91b43c79859032dc95cbfe5 schema:name doi
39 schema:value 10.1007/s10600-010-9583-8
40 rdf:type schema:PropertyValue
41 Nc9b27a6ccdcf4716812ce88008afe751 schema:name Springer Nature - SN SciGraph project
42 rdf:type schema:Organization
43 Nd5bcb07a65ac459998929719f32207d6 rdf:first sg:person.015706066705.62
44 rdf:rest rdf:nil
45 Nf4bd7c73d8b6411a957d9f1d2729cbcf schema:name readcube_id
46 schema:value f54b4bf18369dcb52a7b61aa5d8db9a0ef3d18e8a83f05a3c961549f17d9d15e
47 rdf:type schema:PropertyValue
48 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
49 schema:name Chemical Sciences
50 rdf:type schema:DefinedTerm
51 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
52 schema:name Organic Chemistry
53 rdf:type schema:DefinedTerm
54 sg:journal.1009660 schema:issn 0009-3130
55 1573-8388
56 schema:name Chemistry of Natural Compounds
57 rdf:type schema:Periodical
58 sg:person.014233004507.42 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
59 schema:familyName Abdurazakov
60 schema:givenName A. Sh.
61 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014233004507.42
62 rdf:type schema:Person
63 sg:person.015706066705.62 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
64 schema:familyName Shakhidoyatov
65 schema:givenName Kh. M.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62
67 rdf:type schema:Person
68 sg:person.016612326652.48 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
69 schema:familyName Elmuradov
70 schema:givenName B. Zh.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016612326652.48
72 rdf:type schema:Person
73 https://www.grid.ac/institutes/grid.419209.7 schema:alternateName Academy of Sciences Republic of Uzbekistan
74 schema:name S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
75 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...