Crystal structures of vasicinone and peganidine hydrochloride View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-03

AUTHORS

R. Ya. Okmanov, B. Tashkhodzhaev, Z. M. Khakimova, T. S. Tulyaganov, Kh. M. Shakhidoyatov

ABSTRACT

Crystal structures of the alkaloids vasicinone and peganidine hydrochloride were studied by x-ray structure analysis. The configurations of asymmetric centers C4 and C9 in peganidine were determined. The hydroxyl and acetonyl groups were mutually syn-positioned relative to the tricyclic plane. H-bonds involving the Cl ion, which connected molecular cations transformed by 21 screw axes, were formed in the peganidine hydrochloride crystal. H-bonds between the C4 carbonyl and the C9 hydroxyl transformed by a glide plane were formed in the vasicinone crystal. The N1 atom was not involved in forming intermolecular H-bonds. More... »

PAGES

59-61

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10600-010-9524-6

DOI

http://dx.doi.org/10.1007/s10600-010-9524-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009347616


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0307", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Theoretical and Computational Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Okmanov", 
        "givenName": "R. Ya.", 
        "id": "sg:person.01146674372.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01146674372.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tashkhodzhaev", 
        "givenName": "B.", 
        "id": "sg:person.013557670556.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013557670556.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khakimova", 
        "givenName": "Z. M.", 
        "id": "sg:person.015026076757.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015026076757.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tulyaganov", 
        "givenName": "T. S.", 
        "id": "sg:person.01322302051.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01322302051.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Academy of Sciences Republic of Uzbekistan", 
          "id": "https://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shakhidoyatov", 
        "givenName": "Kh. M.", 
        "id": "sg:person.015706066705.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0957-4166(95)00412-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036745433"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-03", 
    "datePublishedReg": "2010-03-01", 
    "description": "Crystal structures of the alkaloids vasicinone and peganidine hydrochloride were studied by x-ray structure analysis. The configurations of asymmetric centers C4 and C9 in peganidine were determined. The hydroxyl and acetonyl groups were mutually syn-positioned relative to the tricyclic plane. H-bonds involving the Cl ion, which connected molecular cations transformed by 21 screw axes, were formed in the peganidine hydrochloride crystal. H-bonds between the C4 carbonyl and the C9 hydroxyl transformed by a glide plane were formed in the vasicinone crystal. The N1 atom was not involved in forming intermolecular H-bonds.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.1007/s10600-010-9524-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1009660", 
        "issn": [
          "0009-3130", 
          "1573-8388"
        ], 
        "name": "Chemistry of Natural Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "name": "Crystal structures of vasicinone and peganidine hydrochloride", 
    "pagination": "59-61", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "2c877378fa906e120d11fd532f83b98b3eb1cb88fccf0e1c38b7b7c8e6c8cc2b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10600-010-9524-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1009347616"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10600-010-9524-6", 
      "https://app.dimensions.ai/details/publication/pub.1009347616"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T10:16", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000348_0000000348/records_54301_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10600-010-9524-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9524-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9524-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9524-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10600-010-9524-6'


 

This table displays all metadata directly associated to this object as RDF triples.

92 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10600-010-9524-6 schema:about anzsrc-for:03
2 anzsrc-for:0307
3 schema:author N2c41581e354b42bf8c439b4d63acdbf5
4 schema:citation https://doi.org/10.1016/0957-4166(95)00412-2
5 schema:datePublished 2010-03
6 schema:datePublishedReg 2010-03-01
7 schema:description Crystal structures of the alkaloids vasicinone and peganidine hydrochloride were studied by x-ray structure analysis. The configurations of asymmetric centers C4 and C9 in peganidine were determined. The hydroxyl and acetonyl groups were mutually syn-positioned relative to the tricyclic plane. H-bonds involving the Cl ion, which connected molecular cations transformed by 21 screw axes, were formed in the peganidine hydrochloride crystal. H-bonds between the C4 carbonyl and the C9 hydroxyl transformed by a glide plane were formed in the vasicinone crystal. The N1 atom was not involved in forming intermolecular H-bonds.
8 schema:genre non_research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N7d8d0976adf7460eb6126f32c0c4f386
12 Na7ae48ea686f4e308c90bc375c7a79fa
13 sg:journal.1009660
14 schema:name Crystal structures of vasicinone and peganidine hydrochloride
15 schema:pagination 59-61
16 schema:productId Nbec81dcca6164cbda3158cf504dac7d0
17 Ne089bb31709e4187959cfc9c20f9bdc9
18 Nfcc91e4f47db48a5abc0f1004b27497c
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009347616
20 https://doi.org/10.1007/s10600-010-9524-6
21 schema:sdDatePublished 2019-04-11T10:16
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher Nab0075591362446b863bf29369e55036
24 schema:url http://link.springer.com/10.1007%2Fs10600-010-9524-6
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N0eddf9f10307465bbf9528ba494a6f2e rdf:first sg:person.01322302051.34
29 rdf:rest Nd4b52c5f604342e0a19aa4d0a993525b
30 N2c41581e354b42bf8c439b4d63acdbf5 rdf:first sg:person.01146674372.29
31 rdf:rest N6e2e37f6f3e4434d85f362532fe4661b
32 N6e2e37f6f3e4434d85f362532fe4661b rdf:first sg:person.013557670556.88
33 rdf:rest Nfd72ea8a331f41edb68ecd55b22c2f03
34 N7d8d0976adf7460eb6126f32c0c4f386 schema:issueNumber 1
35 rdf:type schema:PublicationIssue
36 Na7ae48ea686f4e308c90bc375c7a79fa schema:volumeNumber 46
37 rdf:type schema:PublicationVolume
38 Nab0075591362446b863bf29369e55036 schema:name Springer Nature - SN SciGraph project
39 rdf:type schema:Organization
40 Nbec81dcca6164cbda3158cf504dac7d0 schema:name doi
41 schema:value 10.1007/s10600-010-9524-6
42 rdf:type schema:PropertyValue
43 Nd4b52c5f604342e0a19aa4d0a993525b rdf:first sg:person.015706066705.62
44 rdf:rest rdf:nil
45 Ne089bb31709e4187959cfc9c20f9bdc9 schema:name dimensions_id
46 schema:value pub.1009347616
47 rdf:type schema:PropertyValue
48 Nfcc91e4f47db48a5abc0f1004b27497c schema:name readcube_id
49 schema:value 2c877378fa906e120d11fd532f83b98b3eb1cb88fccf0e1c38b7b7c8e6c8cc2b
50 rdf:type schema:PropertyValue
51 Nfd72ea8a331f41edb68ecd55b22c2f03 rdf:first sg:person.015026076757.81
52 rdf:rest N0eddf9f10307465bbf9528ba494a6f2e
53 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
54 schema:name Chemical Sciences
55 rdf:type schema:DefinedTerm
56 anzsrc-for:0307 schema:inDefinedTermSet anzsrc-for:
57 schema:name Theoretical and Computational Chemistry
58 rdf:type schema:DefinedTerm
59 sg:journal.1009660 schema:issn 0009-3130
60 1573-8388
61 schema:name Chemistry of Natural Compounds
62 rdf:type schema:Periodical
63 sg:person.01146674372.29 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
64 schema:familyName Okmanov
65 schema:givenName R. Ya.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01146674372.29
67 rdf:type schema:Person
68 sg:person.01322302051.34 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
69 schema:familyName Tulyaganov
70 schema:givenName T. S.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01322302051.34
72 rdf:type schema:Person
73 sg:person.013557670556.88 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
74 schema:familyName Tashkhodzhaev
75 schema:givenName B.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013557670556.88
77 rdf:type schema:Person
78 sg:person.015026076757.81 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
79 schema:familyName Khakimova
80 schema:givenName Z. M.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015026076757.81
82 rdf:type schema:Person
83 sg:person.015706066705.62 schema:affiliation https://www.grid.ac/institutes/grid.419209.7
84 schema:familyName Shakhidoyatov
85 schema:givenName Kh. M.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62
87 rdf:type schema:Person
88 https://doi.org/10.1016/0957-4166(95)00412-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036745433
89 rdf:type schema:CreativeWork
90 https://www.grid.ac/institutes/grid.419209.7 schema:alternateName Academy of Sciences Republic of Uzbekistan
91 schema:name S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan
92 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...