[3+2] Cycloaddition reactions of 1-substituted 3,3,3-trifluoropropenes with isonitriles – synthesis of pyrroles and pyrrolines View Full Text


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Article Info

DATE

2021-03-24

AUTHORS

Yuriy N. Markitanov, Vadim M. Timoshenko, Eduard B. Rusanov, Yuriy G. Shermolovich

ABSTRACT

Cycloaddition reactions of 3,3,3-trifluoropropene derivatives containing an alkoxycarbonyl, sulfonyl, sulfoximine, or sulfamide substituent in position 1 with ethyl isocyanoacetate proceed with the formation of 3-(trifluoromethyl)-2,3-dihydro-1H-pyrroles, whereas their reactions with tosylmethyl isocyanide lead to the formation of 4-(trifluoromethyl)-1H-pyrroles.

PAGES

253-260

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-021-02901-x

DOI

http://dx.doi.org/10.1007/s10593-021-02901-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1136647281


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