Cyclopropanation of areno-condensed 4H-pyrans with dihalocarbenes View Full Text


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Article Info

DATE

2020-11

AUTHORS

Irina А. Semenova, Vitaly А. Osyanin, Maxim R. Demidov, Dmitry V. Osipov, Yuri N. Klimochkin

ABSTRACT

The addition of dihalocarbenes to 1H-benzo[f]chromenes and 4H-chromenes gave a number of dihalotetrahydro(benzo)cyclopropa[b]-chromenes containing donor and acceptor substituents at different positions. It was found that in the case of 1,3-disubstituted 1H-benzo[f]-chromenes, the reaction proceeds diastereoselectively with the formation of trans-isomers. 12H,13H-7a,12a-Methanobenzo[f]indeno-[1,2-b]chromene and 12,13-dihydro-14H-7a,13a-methanodibenzo[a,h]xanthene, representatives of new heterocyclic systems, were obtained.

PAGES

1417-1422

References to SciGraph publications

  • 1987-02. Synthesis of 1-benzoxepines from dichlorocarbene adducts of chromenes in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1982-02. Reaction of dihalocarbenes with chromenes under interphase-catalysis conditions in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
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    http://scigraph.springernature.com/pub.10.1007/s10593-020-02831-0

    DOI

    http://dx.doi.org/10.1007/s10593-020-02831-0

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