Reactions of perfluoroacylchromenes with aromatic amines: synthesis of perfluoroalkylchromene carbaldehydes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-08

AUTHORS

Dmitry V. Osipov, Irina V. Melnikova, Kirill S. Korzhenko, Vitaly A. Osyanin, Yuri N. Klimochkin

ABSTRACT

The reactions of 3-perfluoroacyl-4Н-chromenes and 2-perfluoroacyl-1Н-benzo[f]chromenes with primary aromatic amines resulted in pyran ring cleavage, which was initiated by an aza-Michael reaction. The obtained enamino ketones underwent rearrangements in the presence of superacids, giving 2-perfluoroalkyl-4Н-chromene-3-carbaldehydes and 3-perfluoroalkyl-1Н-benzo[f]chromene-2-carbaldehydes, respectively.

PAGES

990-996

References to SciGraph publications

  • 2016-12. Synthesis of benzo[f]coumarins from 2-trifluoroacetyl-1H-benzo[f]chromenes and 2-naphthols in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2016-08. The rearrangement of trifluoroacetylchromenes to trifluoromethylchromenols in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2016-12. Reaction of 2-chloromethylphenols with enaminones in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10593-020-02765-7

    DOI

    http://dx.doi.org/10.1007/s10593-020-02765-7

    DIMENSIONS

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