Reactions of naphthalen-2-ol Mannich bases with β-aminoacrylonitriles and methyl 3-morpholinoacrylate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-05

AUTHORS

Anton V. Lukashenko, Dmitry V. Osipov, Vitaly А. Osyanin, Yuri N. Klimochkin

ABSTRACT

3-Amino-2,3-dihydro-1H-benzo[f]chromenes and 2-[(2-hydroxynaphthalen-1-yl)methyl]-2,3-dihydro-1H-benzo[f]chromene-2-carbonitriles were obtained via the reaction of naphthalen-2-ol Mannich bases with β-aminoacrylonitriles and methyl 3-morpholinoacrylate as products of [4+2] cycloaddition of push-pull olefins to the corresponding 1,2-naphthoquinone 1-methide. The reaction of 3-amino-3-phenylacrylonitrile with Mannich bases leads to the formation of 1,4-dihydropyridine-3,5-dicarbonitriles.

PAGES

529-536

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-020-02695-4

DOI

http://dx.doi.org/10.1007/s10593-020-02695-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1128275608


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia", 
          "id": "http://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lukashenko", 
        "givenName": "Anton V.", 
        "id": "sg:person.010051317453.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010051317453.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia", 
          "id": "http://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Osipov", 
        "givenName": "Dmitry V.", 
        "id": "sg:person.0774140267.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0774140267.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia", 
          "id": "http://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Osyanin", 
        "givenName": "Vitaly \u0410.", 
        "id": "sg:person.01214150106.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01214150106.35"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia", 
          "id": "http://www.grid.ac/institutes/grid.445792.9", 
          "name": [
            "Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Klimochkin", 
        "givenName": "Yuri N.", 
        "id": "sg:person.07436126201.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07436126201.08"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf00758629", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030158569", 
          "https://doi.org/10.1007/bf00758629"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2020-05", 
    "datePublishedReg": "2020-05-01", 
    "description": "3-Amino-2,3-dihydro-1H-benzo[f]chromenes and 2-[(2-hydroxynaphthalen-1-yl)methyl]-2,3-dihydro-1H-benzo[f]chromene-2-carbonitriles were obtained via the reaction of naphthalen-2-ol Mannich bases with \u03b2-aminoacrylonitriles and methyl 3-morpholinoacrylate as products of [4+2] cycloaddition of push-pull olefins to the corresponding 1,2-naphthoquinone 1-methide. The reaction of 3-amino-3-phenylacrylonitrile with Mannich bases leads to the formation of 1,4-dihydropyridine-3,5-dicarbonitriles.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-020-02695-4", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.8736738", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1358699", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "Mannich bases", 
      "methyl", 
      "dihydropyridines", 
      "dihydro-1H", 
      "reaction", 
      "basis", 
      "aminoacrylonitrile", 
      "carbonitrile", 
      "formation", 
      "products", 
      "dicarbonitrile", 
      "products of cycloaddition", 
      "push-pull olefins", 
      "olefins", 
      "cycloaddition", 
      "naphthalen-2-ol Mannich bases"
    ], 
    "name": "Reactions of naphthalen-2-ol Mannich bases with \u03b2-aminoacrylonitriles and methyl 3-morpholinoacrylate", 
    "pagination": "529-536", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1128275608"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-020-02695-4"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-020-02695-4", 
      "https://app.dimensions.ai/details/publication/pub.1128275608"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_865.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-020-02695-4"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-020-02695-4'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-020-02695-4'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-020-02695-4'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-020-02695-4'


 

This table displays all metadata directly associated to this object as RDF triples.

101 TRIPLES      22 PREDICATES      43 URIs      34 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-020-02695-4 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N3c5599bd645c4b74a735224c5d589492
4 schema:citation sg:pub.10.1007/bf00758629
5 schema:datePublished 2020-05
6 schema:datePublishedReg 2020-05-01
7 schema:description 3-Amino-2,3-dihydro-1H-benzo[f]chromenes and 2-[(2-hydroxynaphthalen-1-yl)methyl]-2,3-dihydro-1H-benzo[f]chromene-2-carbonitriles were obtained via the reaction of naphthalen-2-ol Mannich bases with β-aminoacrylonitriles and methyl 3-morpholinoacrylate as products of [4+2] cycloaddition of push-pull olefins to the corresponding 1,2-naphthoquinone 1-methide. The reaction of 3-amino-3-phenylacrylonitrile with Mannich bases leads to the formation of 1,4-dihydropyridine-3,5-dicarbonitriles.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N9957f2e09abe42848ce81a6bae24e434
12 Nac3bd065eff944beb58d05bad44dd44c
13 sg:journal.1358699
14 schema:keywords Mannich bases
15 aminoacrylonitrile
16 basis
17 carbonitrile
18 cycloaddition
19 dicarbonitrile
20 dihydro-1H
21 dihydropyridines
22 formation
23 methyl
24 naphthalen-2-ol Mannich bases
25 olefins
26 products
27 products of cycloaddition
28 push-pull olefins
29 reaction
30 schema:name Reactions of naphthalen-2-ol Mannich bases with β-aminoacrylonitriles and methyl 3-morpholinoacrylate
31 schema:pagination 529-536
32 schema:productId N2fe2df9dd31046679af66058e2fd81c2
33 N8f5bd46707cc4d93b638f5c217e6cbf9
34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1128275608
35 https://doi.org/10.1007/s10593-020-02695-4
36 schema:sdDatePublished 2022-01-01T18:55
37 schema:sdLicense https://scigraph.springernature.com/explorer/license/
38 schema:sdPublisher N13dae0676e9842bb9a80699689c79e9b
39 schema:url https://doi.org/10.1007/s10593-020-02695-4
40 sgo:license sg:explorer/license/
41 sgo:sdDataset articles
42 rdf:type schema:ScholarlyArticle
43 N13dae0676e9842bb9a80699689c79e9b schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 N2fe2df9dd31046679af66058e2fd81c2 schema:name doi
46 schema:value 10.1007/s10593-020-02695-4
47 rdf:type schema:PropertyValue
48 N3c440e891a444dabb2201f8dd670be1c rdf:first sg:person.01214150106.35
49 rdf:rest Nd3c836904d054ccf9a8015f9af1380f2
50 N3c5599bd645c4b74a735224c5d589492 rdf:first sg:person.010051317453.64
51 rdf:rest Nba88506ce37045e58dc3664d629f878e
52 N8f5bd46707cc4d93b638f5c217e6cbf9 schema:name dimensions_id
53 schema:value pub.1128275608
54 rdf:type schema:PropertyValue
55 N9957f2e09abe42848ce81a6bae24e434 schema:volumeNumber 56
56 rdf:type schema:PublicationVolume
57 Nac3bd065eff944beb58d05bad44dd44c schema:issueNumber 5
58 rdf:type schema:PublicationIssue
59 Nba88506ce37045e58dc3664d629f878e rdf:first sg:person.0774140267.77
60 rdf:rest N3c440e891a444dabb2201f8dd670be1c
61 Nd3c836904d054ccf9a8015f9af1380f2 rdf:first sg:person.07436126201.08
62 rdf:rest rdf:nil
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
67 schema:name Organic Chemistry
68 rdf:type schema:DefinedTerm
69 sg:grant.8736738 http://pending.schema.org/fundedItem sg:pub.10.1007/s10593-020-02695-4
70 rdf:type schema:MonetaryGrant
71 sg:journal.1358699 schema:issn 0132-6244
72 1573-8353
73 schema:name Chemistry of Heterocyclic Compounds
74 schema:publisher Springer Nature
75 rdf:type schema:Periodical
76 sg:person.010051317453.64 schema:affiliation grid-institutes:grid.445792.9
77 schema:familyName Lukashenko
78 schema:givenName Anton V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010051317453.64
80 rdf:type schema:Person
81 sg:person.01214150106.35 schema:affiliation grid-institutes:grid.445792.9
82 schema:familyName Osyanin
83 schema:givenName Vitaly А.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01214150106.35
85 rdf:type schema:Person
86 sg:person.07436126201.08 schema:affiliation grid-institutes:grid.445792.9
87 schema:familyName Klimochkin
88 schema:givenName Yuri N.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07436126201.08
90 rdf:type schema:Person
91 sg:person.0774140267.77 schema:affiliation grid-institutes:grid.445792.9
92 schema:familyName Osipov
93 schema:givenName Dmitry V.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0774140267.77
95 rdf:type schema:Person
96 sg:pub.10.1007/bf00758629 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030158569
97 https://doi.org/10.1007/bf00758629
98 rdf:type schema:CreativeWork
99 grid-institutes:grid.445792.9 schema:alternateName Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia
100 schema:name Samara State Technical University, 244 Molodogvardeyskaya St, 443100, Samara, Russia
101 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...