Synthesis of 4-polyfluoroalkyl-1,3-dithiolanes via [3+2] cycloaddition of thiocarbonyl ylide to polyfluoroalkanethioamides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-02

AUTHORS

Sergiy S. Mykhaylychenko, Yuriy N. Markitanov, Timofii V. Rudenko, Eduard B. Rusanov, Yuriy G. Shermolovich

ABSTRACT

New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.

PAGES

189-192

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-019-02438-0

DOI

http://dx.doi.org/10.1007/s10593-019-02438-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112902282


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mykhaylychenko", 
        "givenName": "Sergiy S.", 
        "id": "sg:person.015735771371.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015735771371.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Markitanov", 
        "givenName": "Yuriy N.", 
        "id": "sg:person.010013161627.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010013161627.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Enamine Ltd., 78 Krasnotkatska St, 02094, Kyiv, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.482870.1", 
          "name": [
            "Enamine Ltd., 78 Krasnotkatska St, 02094, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rudenko", 
        "givenName": "Timofii V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "Eduard B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shermolovich", 
        "givenName": "Yuriy G.", 
        "id": "sg:person.013103553321.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013103553321.47"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1070428013110031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029367483", 
          "https://doi.org/10.1134/s1070428013110031"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-015-1787-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020177841", 
          "https://doi.org/10.1007/s10593-015-1787-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-018-2199-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100198437", 
          "https://doi.org/10.1007/s10593-018-2199-9"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-02", 
    "datePublishedReg": "2019-02-01", 
    "description": "New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-019-02438-0", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "55"
      }
    ], 
    "keywords": [
      "situ", 
      "sulfide", 
      "fluoride", 
      "reaction", 
      "synthesis", 
      "tetramethylammonium fluoride", 
      "dithiolanes", 
      "chloromethyl", 
      "cycloaddition", 
      "desilylation", 
      "thiocarbonyl"
    ], 
    "name": "Synthesis of 4-polyfluoroalkyl-1,3-dithiolanes via [3+2] cycloaddition of thiocarbonyl ylide to polyfluoroalkanethioamides", 
    "pagination": "189-192", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112902282"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-019-02438-0"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-019-02438-0", 
      "https://app.dimensions.ai/details/publication/pub.1112902282"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:45", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_804.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-019-02438-0"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-019-02438-0'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-019-02438-0'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-019-02438-0'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-019-02438-0'


 

This table displays all metadata directly associated to this object as RDF triples.

110 TRIPLES      21 PREDICATES      39 URIs      28 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-019-02438-0 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N36dc31a469f64fb8892f6f6ee607a8c3
4 schema:citation sg:pub.10.1007/s10593-015-1787-1
5 sg:pub.10.1007/s10593-018-2199-9
6 sg:pub.10.1134/s1070428013110031
7 schema:datePublished 2019-02
8 schema:datePublishedReg 2019-02-01
9 schema:description New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.
10 schema:genre article
11 schema:isAccessibleForFree false
12 schema:isPartOf N787d803adb804c858c8b8d93d31b1c91
13 N85b84c40729e4579ab7b2440cd7c08c3
14 sg:journal.1429545
15 schema:keywords chloromethyl
16 cycloaddition
17 desilylation
18 dithiolanes
19 fluoride
20 reaction
21 situ
22 sulfide
23 synthesis
24 tetramethylammonium fluoride
25 thiocarbonyl
26 schema:name Synthesis of 4-polyfluoroalkyl-1,3-dithiolanes via [3+2] cycloaddition of thiocarbonyl ylide to polyfluoroalkanethioamides
27 schema:pagination 189-192
28 schema:productId N347a5400642840ff80a5d6bd6270d8f5
29 N4265b6ce63cc4eb58c07a72ef8a48532
30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112902282
31 https://doi.org/10.1007/s10593-019-02438-0
32 schema:sdDatePublished 2022-10-01T06:45
33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
34 schema:sdPublisher N711a077899ae49bcac4223b7c6b76bfc
35 schema:url https://doi.org/10.1007/s10593-019-02438-0
36 sgo:license sg:explorer/license/
37 sgo:sdDataset articles
38 rdf:type schema:ScholarlyArticle
39 N347a5400642840ff80a5d6bd6270d8f5 schema:name dimensions_id
40 schema:value pub.1112902282
41 rdf:type schema:PropertyValue
42 N36dc31a469f64fb8892f6f6ee607a8c3 rdf:first sg:person.015735771371.86
43 rdf:rest Nb255bf4eb6a24c21849625736a4aef3c
44 N4265b6ce63cc4eb58c07a72ef8a48532 schema:name doi
45 schema:value 10.1007/s10593-019-02438-0
46 rdf:type schema:PropertyValue
47 N538fbde596e943c18bb66a9c4d6ba672 schema:affiliation grid-institutes:grid.482870.1
48 schema:familyName Rudenko
49 schema:givenName Timofii V.
50 rdf:type schema:Person
51 N711a077899ae49bcac4223b7c6b76bfc schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 N787d803adb804c858c8b8d93d31b1c91 schema:issueNumber 2
54 rdf:type schema:PublicationIssue
55 N83e8fe8b41c640bd90156c3ac5a72a76 rdf:first sg:person.01247600537.28
56 rdf:rest Ne3381dc93b0e4875aa497d16d7ff5c3a
57 N85b84c40729e4579ab7b2440cd7c08c3 schema:volumeNumber 55
58 rdf:type schema:PublicationVolume
59 Nb255bf4eb6a24c21849625736a4aef3c rdf:first sg:person.010013161627.52
60 rdf:rest Nce849d56d4f041e0bb00738649c7026e
61 Nce849d56d4f041e0bb00738649c7026e rdf:first N538fbde596e943c18bb66a9c4d6ba672
62 rdf:rest N83e8fe8b41c640bd90156c3ac5a72a76
63 Ne3381dc93b0e4875aa497d16d7ff5c3a rdf:first sg:person.013103553321.47
64 rdf:rest rdf:nil
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
69 schema:name Organic Chemistry
70 rdf:type schema:DefinedTerm
71 sg:journal.1429545 schema:issn 0132-6244
72 1573-8353
73 schema:name Chemistry of Heterocyclic Compounds
74 schema:publisher Springer Nature
75 rdf:type schema:Periodical
76 sg:person.010013161627.52 schema:affiliation grid-institutes:grid.464621.3
77 schema:familyName Markitanov
78 schema:givenName Yuriy N.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010013161627.52
80 rdf:type schema:Person
81 sg:person.01247600537.28 schema:affiliation grid-institutes:grid.464621.3
82 schema:familyName Rusanov
83 schema:givenName Eduard B.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
85 rdf:type schema:Person
86 sg:person.013103553321.47 schema:affiliation grid-institutes:grid.464621.3
87 schema:familyName Shermolovich
88 schema:givenName Yuriy G.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013103553321.47
90 rdf:type schema:Person
91 sg:person.015735771371.86 schema:affiliation grid-institutes:grid.464621.3
92 schema:familyName Mykhaylychenko
93 schema:givenName Sergiy S.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015735771371.86
95 rdf:type schema:Person
96 sg:pub.10.1007/s10593-015-1787-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020177841
97 https://doi.org/10.1007/s10593-015-1787-1
98 rdf:type schema:CreativeWork
99 sg:pub.10.1007/s10593-018-2199-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100198437
100 https://doi.org/10.1007/s10593-018-2199-9
101 rdf:type schema:CreativeWork
102 sg:pub.10.1134/s1070428013110031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029367483
103 https://doi.org/10.1134/s1070428013110031
104 rdf:type schema:CreativeWork
105 grid-institutes:grid.464621.3 schema:alternateName Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine
106 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St, 02660, Kyiv, Ukraine
107 rdf:type schema:Organization
108 grid-institutes:grid.482870.1 schema:alternateName Enamine Ltd., 78 Krasnotkatska St, 02094, Kyiv, Ukraine
109 schema:name Enamine Ltd., 78 Krasnotkatska St, 02094, Kyiv, Ukraine
110 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...