Reaction of cross-conjugated push-pull enamino ketones with 1,2-naphthoquinone 1-methides: synthesis of 3-aryl-1-(1H-benzo[f]chromen-2-yl)prop-2-en-1-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10

AUTHORS

Kirill S. Korzhenko, Dmitry V. Osipov, Vitaly A. Osyanin, Pavel E. Krasnikov, Yuri N. Klimochkin

ABSTRACT

A series of 3-aryl-1-(1H-benzo[f]chromen-2-yl)prop-2-en-1-ones, both unsubstituted and containing an aryl substituent at the C-1 position was obtained via the reaction of cross-conjugated push-push enamino ketones with 2-naphthol-derived Mannich bases. The cascade process involves the hetero-Diels–Alder reaction between 1,2-naphthoquinone 1-methide formed in situ and an enaminone, followed by the elimination of a dimethylamine molecule. More... »

PAGES

940-945

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-018-2377-9

DOI

http://dx.doi.org/10.1007/s10593-018-2377-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110065149


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