Silacyclophanones 2*. Cyclic organosilicon esters of terephthalic acid View Full Text


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Article Info

DATE

2018-08

AUTHORS

Sergey V. Basenko, Anastasiya S. Soldatenko, Olexandr V. Vashchenko, Vladimir I. Smirnov

ABSTRACT

The reactions of dichlorodimethylsilane or 1,3-dichlorotetramethyldisiloxane with bis(trimethylsilyl) ester of terephthalic acid (1:1 molar ratio, 20°C, 72–144 h) gave 69–97% yields of previously unknown 27- and 22-membered cyclic organosilicon esters of terephthalic acid, respectively. The molecular structures of 22-membered ester 4,4,6,6,12,12,14,14-octamethyl-3,5,7,11,13,15-hexaoxa-4,6,12,14-tetrasila-1,9(1,4)-dibenzacyclohexadecaphane-2,8,10,16-tetraone and trimethylsilyl ester of terephthalic acid were studied by X-ray structural analysis. More... »

PAGES

826-828

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-018-2357-0

DOI

http://dx.doi.org/10.1007/s10593-018-2357-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107362561


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