An alternative approach to the synthesis of 5H-chromeno[4,3-b]pyridin-5-one system using the cleavage of 5H,9H-pyrano[2',3':5,6]chromeno[4,3-b]pyridine-5,9-diones with binucleophiles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-01

AUTHORS

Oleg A. Lozinski, Tatyana V. Shokol, Roman I. Zubatyuk, Oleg V. Shishkin, Volodymir P. Khilya

ABSTRACT

Hantzsch reaction has been successfully employed for a one-step assembling of pyranopyridine fragment to produce 5Н,9Н-pyrano[2',3':5,6]- chromeno[4,3-b]pyridine-5,9-diones which upon treatment with binucleophiles undergo chemoselective γ-pyrone ring opening with the concomitant recyclization to give five-membered cycles, providing a concise route to 6-pyrazolyl(isoxazolyl)-5H-chromeno[4,3-b]- pyridin-5-ones.

PAGES

96-99

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-018-2238-6

DOI

http://dx.doi.org/10.1007/s10593-018-2238-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101142936


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