Aminomethylation of Guareschi imides: synthesis of 2,4-dioxo-1H,5H-3,7-spiro[diazabicyclo[3.3.1]nonane-9,4'-piperidine]-1,5-dicarbonitriles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-08

AUTHORS

Anastasiya N. Khrustaleva, Konstantin A. Frolov, Victor V. Dotsenko, Nikolai A. Aksenov, Inna V. Aksenova, Sergey G. Krivokolysko

ABSTRACT

The aminomethylation reaction of 9-benzyl-2,4-dioxo-3,9-diazaspiro[5.5]undecane-1,5-dicarbonitrile hydrochloride in the presence of primary aliphatic amines and an excess of 37% aqueous formaldehyde led to the formation of 7-substituted 1'-benzyl-2,4-dioxo-1H,5Hspiro[3,7-diazabicyclo[3.3.1]nonane-9,4'-piperidine]-1,5-dicarbonitrile derivatives.

PAGES

887-891

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-017-2140-7

DOI

http://dx.doi.org/10.1007/s10593-017-2140-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1092086594


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