Reaction of enamino pyrrolidide and piperidide of 2,2-dimethyl-1,2,3,4-tetrahydrobenz[f]isoquinoline series with ninhydrin View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-10

AUTHORS

Alexander G. Mikhailovskii, Denis V. Korchagin, Alexey S. Yusov, Oksana V. Gashkova

ABSTRACT

Interaction of (4Z)-2,2-dimethyl-4-(2-oxo-2-pyrrolidin-1-ylethylidene)-1,2,3,4-tetrahydrobenz[f]isoquinoline with ninhydrin leads to annulation of an indeno[1,2-b]pyrrole ring. An analogous product is formed by replacing of the pyrrolidine ring with the piperidine ring. Further heating of the obtained glycol in the presence of AcOH leads to rearrangement with the formation of benz[f]isochromeno-[4',3':4,5]pyrrolo[2,1-a]isoquinoline hexacyclic system.

PAGES

852-854

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-016-1977-5

DOI

http://dx.doi.org/10.1007/s10593-016-1977-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033552456


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