Recyclization of carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes by the action of amidines and guanidine: a novel method for the synthesis of ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-10

AUTHORS

Yulia V. Popova, Darina V. Sakhnenko, Irina V. Arbuzova, Vitaly A. Osyanin, Dmitry V. Osipov, Yuri N. Klimochkin

ABSTRACT

A series of 2-[(pyrimidin-5-yl)methyl]phenols and 1-[(pyrimidin-5-yl)methyl]-2-naphthols have been accessed via the interaction of carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with amidines and guanidine in a reaction cascade initiated by the Michael reaction. It was established that in this transformation chromenes act as the synthetic equivalents of hydroxybenzylated α-formyl ketones or α-formylaldehydes.

PAGES

803-808

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-016-1969-5

DOI

http://dx.doi.org/10.1007/s10593-016-1969-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043515115


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