Synthesis of 2-Aryl-4,5-Bis(Polyfluoroalkyl)Imidazoles from Polyfluoroalkanethiocarboxylic Acid Amides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-02

AUTHORS

Sergey S. Mykhaylychenko, Nadezhda V. Pikun, Eduard B. Rusanov, Yuriy G. Shermolovich

ABSTRACT

Polyfluoroalkanethiocarboxylic acid amides react with aromatic aldehydes with the formation of bis(N-thioacyl)aminals. Treating the latter with acyl chlorides gives 2-aryl-substituted 4,5-bis(polyfluoroalkyl)imidazoles which constitutes a novel method of synthesizing these imidazole derivatives.

PAGES

128-132

References to SciGraph publications

Journal

TITLE

Chemistry of Heterocyclic Compounds

ISSUE

2

VOLUME

51

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-015-1669-6

DOI

http://dx.doi.org/10.1007/s10593-015-1669-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012344916


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mykhaylychenko", 
        "givenName": "Sergey S.", 
        "id": "sg:person.014153770713.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014153770713.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pikun", 
        "givenName": "Nadezhda V.", 
        "id": "sg:person.015546731713.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015546731713.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "Eduard B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shermolovich", 
        "givenName": "Yuriy G.", 
        "id": "sg:person.014117641017.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014117641017.47"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/00304949909355704", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002520160"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00397910601039192", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003084914"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19600930320", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003261516"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/op700134j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005877997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/op700134j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005877997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cjoc.19940120111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006768908"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cjoc.19940120111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006768908"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2014.09.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014305881"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jlac.18781920102", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018304707"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4039(00)01686-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023513490"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2003.11.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031348483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-1139(00)80360-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040012477"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11178-005-0155-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041343959", 
          "https://doi.org/10.1007/s11178-005-0155-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11178-005-0155-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041343959", 
          "https://doi.org/10.1007/s11178-005-0155-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tetlet.2009.12.064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047611438"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00081a006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055541362"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jf60170a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055920832"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo00076a029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055964991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2174/1568026614666140202210424", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069194896"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-02", 
    "datePublishedReg": "2015-02-01", 
    "description": " Polyfluoroalkanethiocarboxylic acid amides react with aromatic aldehydes with the formation of bis(N-thioacyl)aminals. Treating the latter with acyl chlorides gives 2-aryl-substituted 4,5-bis(polyfluoroalkyl)imidazoles which constitutes a novel method of synthesizing these imidazole derivatives.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10593-015-1669-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "name": "Synthesis of 2-Aryl-4,5-Bis(Polyfluoroalkyl)Imidazoles from Polyfluoroalkanethiocarboxylic Acid Amides", 
    "pagination": "128-132", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3ad0a6f53644e7e3775d8d6a3977539b9fdcc81c914946cc1b5f57ca30e00a34"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-015-1669-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1012344916"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-015-1669-6", 
      "https://app.dimensions.ai/details/publication/pub.1012344916"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:51", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000511.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10593-015-1669-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1669-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1669-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1669-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1669-6'


 

This table displays all metadata directly associated to this object as RDF triples.

126 TRIPLES      20 PREDICATES      42 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-015-1669-6 schema:author Nc4502a7a137040449dc54b1f92a02a12
2 schema:citation sg:pub.10.1007/s11178-005-0155-5
3 https://doi.org/10.1002/cber.19600930320
4 https://doi.org/10.1002/cjoc.19940120111
5 https://doi.org/10.1002/jlac.18781920102
6 https://doi.org/10.1016/j.jfluchem.2003.11.009
7 https://doi.org/10.1016/j.jfluchem.2014.09.006
8 https://doi.org/10.1016/j.tetlet.2009.12.064
9 https://doi.org/10.1016/s0022-1139(00)80360-7
10 https://doi.org/10.1016/s0040-4039(00)01686-5
11 https://doi.org/10.1021/ic00081a006
12 https://doi.org/10.1021/jf60170a013
13 https://doi.org/10.1021/jo00076a029
14 https://doi.org/10.1021/op700134j
15 https://doi.org/10.1080/00304949909355704
16 https://doi.org/10.1080/00397910601039192
17 https://doi.org/10.1107/s0108767307043930
18 https://doi.org/10.2174/1568026614666140202210424
19 schema:datePublished 2015-02
20 schema:datePublishedReg 2015-02-01
21 schema:description Polyfluoroalkanethiocarboxylic acid amides react with aromatic aldehydes with the formation of bis(N-thioacyl)aminals. Treating the latter with acyl chlorides gives 2-aryl-substituted 4,5-bis(polyfluoroalkyl)imidazoles which constitutes a novel method of synthesizing these imidazole derivatives.
22 schema:genre research_article
23 schema:inLanguage en
24 schema:isAccessibleForFree false
25 schema:isPartOf Na6e1b4c5be544f7583fe7798c9062fbc
26 Nfaf907cfeac44b739cd7daeeb01b8483
27 sg:journal.1356886
28 schema:name Synthesis of 2-Aryl-4,5-Bis(Polyfluoroalkyl)Imidazoles from Polyfluoroalkanethiocarboxylic Acid Amides
29 schema:pagination 128-132
30 schema:productId N2afc25ef64144e4780ffbbf3e7071d7f
31 N7eb8b0e043f041a3a7d0b1a2a827d297
32 Nbe5e42d020824192b83be2c7071c8c51
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012344916
34 https://doi.org/10.1007/s10593-015-1669-6
35 schema:sdDatePublished 2019-04-10T15:51
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher N64742c8a05f04d5d99950d5c27f82e31
38 schema:url http://link.springer.com/10.1007%2Fs10593-015-1669-6
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N2afc25ef64144e4780ffbbf3e7071d7f schema:name doi
43 schema:value 10.1007/s10593-015-1669-6
44 rdf:type schema:PropertyValue
45 N64742c8a05f04d5d99950d5c27f82e31 schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 N7e7f2fa7c81c43cdb6857086771c956f rdf:first sg:person.015546731713.34
48 rdf:rest Nd03cbe425a18403284db55eabd29a490
49 N7eb8b0e043f041a3a7d0b1a2a827d297 schema:name dimensions_id
50 schema:value pub.1012344916
51 rdf:type schema:PropertyValue
52 N903adf88e748479180a3a690c94f8e86 rdf:first sg:person.014117641017.47
53 rdf:rest rdf:nil
54 Na6e1b4c5be544f7583fe7798c9062fbc schema:volumeNumber 51
55 rdf:type schema:PublicationVolume
56 Nbe5e42d020824192b83be2c7071c8c51 schema:name readcube_id
57 schema:value 3ad0a6f53644e7e3775d8d6a3977539b9fdcc81c914946cc1b5f57ca30e00a34
58 rdf:type schema:PropertyValue
59 Nc4502a7a137040449dc54b1f92a02a12 rdf:first sg:person.014153770713.47
60 rdf:rest N7e7f2fa7c81c43cdb6857086771c956f
61 Nd03cbe425a18403284db55eabd29a490 rdf:first sg:person.01247600537.28
62 rdf:rest N903adf88e748479180a3a690c94f8e86
63 Nfaf907cfeac44b739cd7daeeb01b8483 schema:issueNumber 2
64 rdf:type schema:PublicationIssue
65 sg:journal.1356886 schema:issn 0009-3122
66 1573-8353
67 schema:name Chemistry of Heterocyclic Compounds
68 rdf:type schema:Periodical
69 sg:person.01247600537.28 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
70 schema:familyName Rusanov
71 schema:givenName Eduard B.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
73 rdf:type schema:Person
74 sg:person.014117641017.47 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
75 schema:familyName Shermolovich
76 schema:givenName Yuriy G.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014117641017.47
78 rdf:type schema:Person
79 sg:person.014153770713.47 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
80 schema:familyName Mykhaylychenko
81 schema:givenName Sergey S.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014153770713.47
83 rdf:type schema:Person
84 sg:person.015546731713.34 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
85 schema:familyName Pikun
86 schema:givenName Nadezhda V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015546731713.34
88 rdf:type schema:Person
89 sg:pub.10.1007/s11178-005-0155-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041343959
90 https://doi.org/10.1007/s11178-005-0155-5
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1002/cber.19600930320 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003261516
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1002/cjoc.19940120111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006768908
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1002/jlac.18781920102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018304707
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1016/j.jfluchem.2003.11.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031348483
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1016/j.jfluchem.2014.09.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014305881
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1016/j.tetlet.2009.12.064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047611438
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1016/s0022-1139(00)80360-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040012477
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/s0040-4039(00)01686-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023513490
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1021/ic00081a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055541362
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1021/jf60170a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055920832
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1021/jo00076a029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055964991
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1021/op700134j schema:sameAs https://app.dimensions.ai/details/publication/pub.1005877997
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1080/00304949909355704 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002520160
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1080/00397910601039192 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003084914
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
121 rdf:type schema:CreativeWork
122 https://doi.org/10.2174/1568026614666140202210424 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069194896
123 rdf:type schema:CreativeWork
124 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
125 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine
126 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...