Revision of 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dien-1-ylidene)malononitrile structure. Molecular and crystal structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile View Full Text


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Article Info

DATE

2015-01

AUTHORS

Vladimir D. Dyachenko, Alexey N. Toropov, Eduard B. Rusanov

ABSTRACT

Upon alkylation of 2-aminoprop-1-ene-1,1,3-tricarbonitrile with phenacyl bromides, 2-(2-aryl-2-oxoethyl)-2-(5-aryl-3-cyano-1Н-pyrrol-2-yl)malononitriles are formed instead of previously presumed isomeric 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dienes. The structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile was studied by X-ray structural analysis.

PAGES

31-33

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z

DOI

http://dx.doi.org/10.1007/s10593-015-1655-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023023093


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