Revision of 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dien-1-ylidene)malononitrile structure. Molecular and crystal structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-01

AUTHORS

Vladimir D. Dyachenko, Alexey N. Toropov, Eduard B. Rusanov

ABSTRACT

Upon alkylation of 2-aminoprop-1-ene-1,1,3-tricarbonitrile with phenacyl bromides, 2-(2-aryl-2-oxoethyl)-2-(5-aryl-3-cyano-1Н-pyrrol-2-yl)malononitriles are formed instead of previously presumed isomeric 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dienes. The structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile was studied by X-ray structural analysis.

PAGES

31-33

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z

DOI

http://dx.doi.org/10.1007/s10593-015-1655-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023023093


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Taras Shevchenko Lugansk National University, 2 Oboronnaya St., 91011, Lugansk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dyachenko", 
        "givenName": "Vladimir D.", 
        "id": "sg:person.014211162307.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014211162307.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Taras Shevchenko Lugansk National University, 2 Oboronnaya St., 91011, Lugansk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Toropov", 
        "givenName": "Alexey N.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institute of Organic Chemistry of the NAS of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "Eduard B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0021889802022112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002150867"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00798796", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017250714", 
          "https://doi.org/10.1007/bf00798796"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00798796", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017250714", 
          "https://doi.org/10.1007/bf00798796"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00798796", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017250714", 
          "https://doi.org/10.1007/bf00798796"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108270197019835", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022701464"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/10426500211711", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032174421"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-011-0833-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042478460", 
          "https://doi.org/10.1007/s10593-011-0833-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767394005726", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046337108"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s007060050308", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053450163", 
          "https://doi.org/10.1007/s007060050308"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-01", 
    "datePublishedReg": "2015-01-01", 
    "description": " Upon alkylation of 2-aminoprop-1-ene-1,1,3-tricarbonitrile with phenacyl bromides, 2-(2-aryl-2-oxoethyl)-2-(5-aryl-3-cyano-1\u041d-pyrrol-2-yl)malononitriles are formed instead of previously presumed isomeric 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dienes. The structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1\u041d-pyrrol-2-yl]malononitrile was studied by X-ray structural analysis.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.1007/s10593-015-1655-z", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "name": "Revision of 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dien-1-ylidene)malononitrile structure. Molecular and crystal structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1\u041d-pyrrol-2-yl]malononitrile", 
    "pagination": "31-33", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "6db0013d4e175b0d3c578e5493bf4649e68d997e3aefcf95e14f8ea197962f2c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-015-1655-z"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1023023093"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-015-1655-z", 
      "https://app.dimensions.ai/details/publication/pub.1023023093"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:31", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000512.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10593-015-1655-z"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-015-1655-z'


 

This table displays all metadata directly associated to this object as RDF triples.

104 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-015-1655-z schema:about anzsrc-for:02
2 anzsrc-for:0299
3 schema:author N31d249557282470fb2e19403c333d657
4 schema:citation sg:pub.10.1007/bf00798796
5 sg:pub.10.1007/s007060050308
6 sg:pub.10.1007/s10593-011-0833-x
7 https://doi.org/10.1080/10426500211711
8 https://doi.org/10.1107/s0021889802022112
9 https://doi.org/10.1107/s0108270197019835
10 https://doi.org/10.1107/s0108767307043930
11 https://doi.org/10.1107/s0108767394005726
12 schema:datePublished 2015-01
13 schema:datePublishedReg 2015-01-01
14 schema:description Upon alkylation of 2-aminoprop-1-ene-1,1,3-tricarbonitrile with phenacyl bromides, 2-(2-aryl-2-oxoethyl)-2-(5-aryl-3-cyano-1Н-pyrrol-2-yl)malononitriles are formed instead of previously presumed isomeric 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dienes. The structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile was studied by X-ray structural analysis.
15 schema:genre non_research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N1c02caa659544d0fa01ccb3e844fab95
19 N8be9405736004336800393ceae21556b
20 sg:journal.1356886
21 schema:name Revision of 2-(3,8-diaryl-6-oxo-2,7-diazaspiro[4.4]nona-2,8-dien-1-ylidene)malononitrile structure. Molecular and crystal structure of 3-cyano-2-[2-(4-methoxyphenyl)-2-oxoethyl]-2-[5-(4-methoxyphenyl)-1Н-pyrrol-2-yl]malononitrile
22 schema:pagination 31-33
23 schema:productId N806e7842541d43a8a1cf4dbd8d682110
24 Ne673f777549f4a308d03847052c3cdd6
25 Nf88ffa2c2fe54f4999de9da9278fb180
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023023093
27 https://doi.org/10.1007/s10593-015-1655-z
28 schema:sdDatePublished 2019-04-10T22:31
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher Nf67985e6b39c4116adbadfe20111fbde
31 schema:url http://link.springer.com/10.1007%2Fs10593-015-1655-z
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N07c9ace9b559446fa4189c90704b427c rdf:first Nffb78162b4014ccb98d8a45a405084ab
36 rdf:rest Na22948e0dd824a399574c75a4dec6a3a
37 N1c02caa659544d0fa01ccb3e844fab95 schema:issueNumber 1
38 rdf:type schema:PublicationIssue
39 N31d249557282470fb2e19403c333d657 rdf:first sg:person.014211162307.92
40 rdf:rest N07c9ace9b559446fa4189c90704b427c
41 N5f3aaa46cc3144d1b46f20ce39b0ac36 schema:name Institute of Organic Chemistry of the NAS of Ukraine, 5 Murmanska St., 02660, Kyiv, Ukraine
42 rdf:type schema:Organization
43 N806e7842541d43a8a1cf4dbd8d682110 schema:name dimensions_id
44 schema:value pub.1023023093
45 rdf:type schema:PropertyValue
46 N8be9405736004336800393ceae21556b schema:volumeNumber 51
47 rdf:type schema:PublicationVolume
48 Na22948e0dd824a399574c75a4dec6a3a rdf:first sg:person.01247600537.28
49 rdf:rest rdf:nil
50 Ne587ef56a9a04d21919c1b9a85dbc254 schema:name Taras Shevchenko Lugansk National University, 2 Oboronnaya St., 91011, Lugansk, Ukraine
51 rdf:type schema:Organization
52 Ne673f777549f4a308d03847052c3cdd6 schema:name readcube_id
53 schema:value 6db0013d4e175b0d3c578e5493bf4649e68d997e3aefcf95e14f8ea197962f2c
54 rdf:type schema:PropertyValue
55 Nf1167c1f8a0a4486ad624e3ac144654d schema:name Taras Shevchenko Lugansk National University, 2 Oboronnaya St., 91011, Lugansk, Ukraine
56 rdf:type schema:Organization
57 Nf67985e6b39c4116adbadfe20111fbde schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 Nf88ffa2c2fe54f4999de9da9278fb180 schema:name doi
60 schema:value 10.1007/s10593-015-1655-z
61 rdf:type schema:PropertyValue
62 Nffb78162b4014ccb98d8a45a405084ab schema:affiliation Nf1167c1f8a0a4486ad624e3ac144654d
63 schema:familyName Toropov
64 schema:givenName Alexey N.
65 rdf:type schema:Person
66 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
67 schema:name Physical Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
70 schema:name Other Physical Sciences
71 rdf:type schema:DefinedTerm
72 sg:journal.1356886 schema:issn 0009-3122
73 1573-8353
74 schema:name Chemistry of Heterocyclic Compounds
75 rdf:type schema:Periodical
76 sg:person.01247600537.28 schema:affiliation N5f3aaa46cc3144d1b46f20ce39b0ac36
77 schema:familyName Rusanov
78 schema:givenName Eduard B.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
80 rdf:type schema:Person
81 sg:person.014211162307.92 schema:affiliation Ne587ef56a9a04d21919c1b9a85dbc254
82 schema:familyName Dyachenko
83 schema:givenName Vladimir D.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014211162307.92
85 rdf:type schema:Person
86 sg:pub.10.1007/bf00798796 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017250714
87 https://doi.org/10.1007/bf00798796
88 rdf:type schema:CreativeWork
89 sg:pub.10.1007/s007060050308 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053450163
90 https://doi.org/10.1007/s007060050308
91 rdf:type schema:CreativeWork
92 sg:pub.10.1007/s10593-011-0833-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1042478460
93 https://doi.org/10.1007/s10593-011-0833-x
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1080/10426500211711 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032174421
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1107/s0021889802022112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002150867
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1107/s0108270197019835 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022701464
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1107/s0108767394005726 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046337108
104 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...