Synthesis and Photochromic Properties of Asymmetric Dihetarylethenes Based on 5-methoxy-1,2-dimethylindole and 5-(4-bromophenyl)-2-methylthiophene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-10

AUTHORS

E. N. Shepelenko, N. I. Makarova, O. G. Karamov, A. D. Dubonosov, V. A. Podshibakin, A. V. Metelitsa, V. A. Bren’, V. I. Minkin

ABSTRACT

We report the synthesis of new asymmetric dihetarylethenes – 4-[5-(4-bromophenyl)-2-methylthiophen-3-yl]-3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)furan-2,5-dione and 1-alkyl(phenyl)-3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-[5-(4-bromophenyl)-2-methylthiophen-3-yl]-1H-pyrrole-2,5-diones, which exhibit photo-chromic and fluorescent properties in solution. Thermally stable photoinduced cyclic isomers were observed for dihetarylethenes derived from 5-methoxy-1,2-dimethylindole and 5-(4-bromophenyl)-2-methylthiophene, unlike for their structural analogs based on 5-methoxy-1,2-dimethylindole and unsubstituted thiophene. Changing the thiophene fragment of dihetarylethenes to a 5-(4-bromophenyl)-2-methylthiophene fragment gave rise to photochromic properties in furan-2,5-dione derivatives. More... »

PAGES

932-940

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-014-1547-7

DOI

http://dx.doi.org/10.1007/s10593-014-1547-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017556366


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