Synthesis and Structure of a New Polydentate 8-Hydroxyquinoline Ligand System with a 1,3-Tropolone Fragment at Position 2 in the Quinoline ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-08-19

AUTHORS

I. E. Mikhailov, A. A. Kolodina, G. A. Dushenko, Yu. M. Artyushkina, V. V. Tkachev, S. M. Aldoshin, Yu. A. Sayapin, V. I. Minkin

ABSTRACT

An original three-step method has been developed for the synthesis of a new polydentate 8-hydroxyquinoline ligand system with a 1,3-tropolone fragment at position 2 of the quinoline ring. X-ray diffraction structural analysis, 1H and 13C NMR spectroscopy, and quantum-chemical calculations showed that this ligand exists in the NH-tautomeric form with the phenolic hydroxyl group in the exo position of the quinoline ring. More... »

PAGES

828-837

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-014-1537-9

DOI

http://dx.doi.org/10.1007/s10593-014-1537-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030274875


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170 grid-institutes:grid.465325.3 schema:alternateName Southern Scientific Center, Russian Academy of Sciences, 41 Chekhov St., 344006, Rostov-on-Don, Russia
171 schema:name Southern Scientific Center, Russian Academy of Sciences, 41 Chekhov St., 344006, Rostov-on-Don, Russia
172 rdf:type schema:Organization
 




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