2013-11-22
AUTHORSA. B. Sheremetev, A. M. Kozeev, N. S. Aleksandrova, M. I. Struchkova, K. Yu. Suponitsky
ABSTRACTThe reactivity of 3-(1-adamantyl)-4-aminofurazan was studied. Upon treatment with oxidizing reagents the amino group is oxidized to azo, azoxy, and nitro groups. The nitration of 3-(1-adamantyl)-4-aminofurazan with nitric acid provided the corresponding nitroamine. The reaction of 3-(1-adamantyl)-4-nitrofurazan with nitrating and bromination agents takes place at the bridgehead position of the adamantane fragment and gives the corresponding nitroxyl and bromo derivatives. An X-ray structural analysis of 4,4′-di(1-adamantyl)azofurazan was undertaken. More... »
PAGES1358-1369
http://scigraph.springernature.com/pub.10.1007/s10593-013-1385-z
DOIhttp://dx.doi.org/10.1007/s10593-013-1385-z
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