3-(1-Adamantyl)Furazans View Full Text


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Article Info

DATE

2013-11-22

AUTHORS

A. B. Sheremetev, A. M. Kozeev, N. S. Aleksandrova, M. I. Struchkova, K. Yu. Suponitsky

ABSTRACT

The reactivity of 3-(1-adamantyl)-4-aminofurazan was studied. Upon treatment with oxidizing reagents the amino group is oxidized to azo, azoxy, and nitro groups. The nitration of 3-(1-adamantyl)-4-aminofurazan with nitric acid provided the corresponding nitroamine. The reaction of 3-(1-adamantyl)-4-nitrofurazan with nitrating and bromination agents takes place at the bridgehead position of the adamantane fragment and gives the corresponding nitroxyl and bromo derivatives. An X-ray structural analysis of 4,4′-di(1-adamantyl)azofurazan was undertaken. More... »

PAGES

1358-1369

References to SciGraph publications

  • 2011-02. Nitration of primary aminofurazans with aqueous nitric acid in RUSSIAN CHEMICAL BULLETIN
  • 1982-01. Orientation in the nitration of 3-phenyl-4-substituted furazans in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2005-02. Reactivity of 3,5-bis-(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-triazole in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2002-02. 1H, 13C, and 14N NMR study of 3-methylfurazans with nitrogen-containing substituents at position 4 in RUSSIAN CHEMICAL BULLETIN
  • 1994-05. Synthesis of diazoxyfurazanes in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1988-02. Properties of furoxans monosubstituted with adamantanes in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1988-08. Synthesis and properties of N-substituted aminofuroxans in the adamantane series in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1993-04. α-Bromoacetyl derivatives of furazan and furoxan in RUSSIAN CHEMICAL BULLETIN
  • 1994-05. Synthesis and properties of 4-amino-3-cyanofurazan in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1960-12. Description of steric relationships across single bonds in CELLULAR AND MOLECULAR LIFE SCIENCES
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10593-013-1385-z

    DOI

    http://dx.doi.org/10.1007/s10593-013-1385-z

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1042762773


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