N-Alkoxy-N-chloroureas in the synthesis of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-alkoxy-1,3-dihydrobenzimidazol-2-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11

AUTHORS

V. G. Shtamburg, O. V. Shishkin, V. V. Shtamburg, R. I. Zubatyuk, A. V. Mazepa, R. G. Kostyanovsky

ABSTRACT

The cyclization of N-chloro-N-(2-phenylethoxy)urea in the presence of silver trifluoroacetate leads to the formation of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide, while N-alkoxy-N'-aryl-N-chloro-ureas in the presence of sodium acetate form 1-alkoxy-1,3-dihydrobenzimidazol-2-ones. The structures of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-methoxy-6-nitro-1,3-dihydrobenzimidazol-2-one were examined by X-ray structural analysis.

PAGES

1195-1206

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-013-1363-5

DOI

http://dx.doi.org/10.1007/s10593-013-1363-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028569833


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Ukrainian State University of Chemical Technology", 
          "id": "https://www.grid.ac/institutes/grid.445406.7", 
          "name": [
            "Ukrainian State University of Chemical Technologies, 8 Gagarin Ave., 49005, Dnipropetrovsk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shtamburg", 
        "givenName": "V. G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "State Scientific Institution \u201cInstitute for Single Crystals\u201d of National Academy of Sciences of Ukraine, 60 Lenina Ave., 61001, Kharkiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shishkin", 
        "givenName": "O. V.", 
        "id": "sg:person.01023575604.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01023575604.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kharkiv Polytechnic Institute", 
          "id": "https://www.grid.ac/institutes/grid.18192.33", 
          "name": [
            "National Technical University, Kharkiv Polytechnic Institute, 21 Frunze St., 61002, Kharkiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shtamburg", 
        "givenName": "V. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "State Scientific Institution \u201cInstitute for Single Crystals\u201d of National Academy of Sciences of Ukraine, 60 Lenina Ave., 61001, Kharkiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zubatyuk", 
        "givenName": "R. I.", 
        "id": "sg:person.0712120430.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0712120430.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, 86 Lyustdorfskaya Road, 65080, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mazepa", 
        "givenName": "A. V.", 
        "id": "sg:person.016173011573.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016173011573.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "N. N. Semenov Institute of Chemical Physics, 4 Kosygina St., 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kostyanovsky", 
        "givenName": "R. G.", 
        "id": "sg:person.015611422615.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015611422615.86"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0040-4020(98)00197-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003990635"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.mencom.2012.05.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005936477"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-2836(71)90419-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008822204"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1070/mc2006v016n06abeh002382", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011902960"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.mencom.2007.05.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014526373"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)81665-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016725449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1070/mc2006v016n04abeh002195", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018019999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chir.20668", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035135721"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.mencom.2011.01.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035985217"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)87905-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041641687"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00331a053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055724017"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm9607921", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055958030"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm9607921", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055958030"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo00275a027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055976768"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-11", 
    "datePublishedReg": "2013-11-01", 
    "description": "The cyclization of N-chloro-N-(2-phenylethoxy)urea in the presence of silver trifluoroacetate leads to the formation of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide, while N-alkoxy-N'-aryl-N-chloro-ureas in the presence of sodium acetate form 1-alkoxy-1,3-dihydrobenzimidazol-2-ones. The structures of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-methoxy-6-nitro-1,3-dihydrobenzimidazol-2-one were examined by X-ray structural analysis.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10593-013-1363-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "49"
      }
    ], 
    "name": "N-Alkoxy-N-chloroureas in the synthesis of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-alkoxy-1,3-dihydrobenzimidazol-2-ones", 
    "pagination": "1195-1206", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "8819347a863c2c5d02cafaf9a9db6463859edbe39bf2ecee3c8f8d665d135d15"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-013-1363-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1028569833"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-013-1363-5", 
      "https://app.dimensions.ai/details/publication/pub.1028569833"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:16", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000513.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10593-013-1363-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1363-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1363-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1363-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1363-5'


 

This table displays all metadata directly associated to this object as RDF triples.

145 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-013-1363-5 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author Ne54cfe757d034f4a805a7e2bbf4b69ea
4 schema:citation https://doi.org/10.1002/chir.20668
5 https://doi.org/10.1016/0022-2836(71)90419-0
6 https://doi.org/10.1016/j.mencom.2007.05.016
7 https://doi.org/10.1016/j.mencom.2011.01.021
8 https://doi.org/10.1016/j.mencom.2012.05.019
9 https://doi.org/10.1016/s0040-4020(01)81665-3
10 https://doi.org/10.1016/s0040-4020(01)87905-9
11 https://doi.org/10.1016/s0040-4020(98)00197-5
12 https://doi.org/10.1021/ja00331a053
13 https://doi.org/10.1021/jm9607921
14 https://doi.org/10.1021/jo00275a027
15 https://doi.org/10.1070/mc2006v016n04abeh002195
16 https://doi.org/10.1070/mc2006v016n06abeh002382
17 schema:datePublished 2013-11
18 schema:datePublishedReg 2013-11-01
19 schema:description The cyclization of N-chloro-N-(2-phenylethoxy)urea in the presence of silver trifluoroacetate leads to the formation of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide, while N-alkoxy-N'-aryl-N-chloro-ureas in the presence of sodium acetate form 1-alkoxy-1,3-dihydrobenzimidazol-2-ones. The structures of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-methoxy-6-nitro-1,3-dihydrobenzimidazol-2-one were examined by X-ray structural analysis.
20 schema:genre research_article
21 schema:inLanguage en
22 schema:isAccessibleForFree false
23 schema:isPartOf N6f045bed8ce243d68d74e74fa43ce073
24 Ncf5a3ee69da248ef9bbbcb7eb5071d4d
25 sg:journal.1356886
26 schema:name N-Alkoxy-N-chloroureas in the synthesis of 3,4-dihydro-1H-2,1-benzoxazine-1-carboxamide and 1-alkoxy-1,3-dihydrobenzimidazol-2-ones
27 schema:pagination 1195-1206
28 schema:productId N3fdeeeee34d746a892120702db2e9bf8
29 N75f3ed291a2b41b08fe5cb6cc2f7cb8f
30 Na8c3150efa724936ba95e20503de6dcd
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028569833
32 https://doi.org/10.1007/s10593-013-1363-5
33 schema:sdDatePublished 2019-04-11T00:16
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher N4e8aeb6bcd5141d8aed3706a71978c59
36 schema:url http://link.springer.com/10.1007%2Fs10593-013-1363-5
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N0510fe67aa4f448b8e7b4ab492f136e8 schema:affiliation https://www.grid.ac/institutes/grid.445406.7
41 schema:familyName Shtamburg
42 schema:givenName V. G.
43 rdf:type schema:Person
44 N09faca243f4c4a6e908151077391c178 rdf:first sg:person.016173011573.64
45 rdf:rest Nc3ea0041ea084fc2a21420fc2f420d9e
46 N1440c6237cdf48e0947c37d6d80eb583 schema:name State Scientific Institution “Institute for Single Crystals” of National Academy of Sciences of Ukraine, 60 Lenina Ave., 61001, Kharkiv, Ukraine
47 rdf:type schema:Organization
48 N37f55998f9c442f4964e185c7714a97c rdf:first N971a548520364ac2b1b70e8e0e90bb70
49 rdf:rest N4be1263ec53b43a1a2f2ecbca9e1a283
50 N3fdeeeee34d746a892120702db2e9bf8 schema:name readcube_id
51 schema:value 8819347a863c2c5d02cafaf9a9db6463859edbe39bf2ecee3c8f8d665d135d15
52 rdf:type schema:PropertyValue
53 N45be4ddfb70f44dbbef5a24ed6220e1d rdf:first sg:person.01023575604.49
54 rdf:rest N37f55998f9c442f4964e185c7714a97c
55 N4be1263ec53b43a1a2f2ecbca9e1a283 rdf:first sg:person.0712120430.13
56 rdf:rest N09faca243f4c4a6e908151077391c178
57 N4e8aeb6bcd5141d8aed3706a71978c59 schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 N6f045bed8ce243d68d74e74fa43ce073 schema:issueNumber 8
60 rdf:type schema:PublicationIssue
61 N75f3ed291a2b41b08fe5cb6cc2f7cb8f schema:name dimensions_id
62 schema:value pub.1028569833
63 rdf:type schema:PropertyValue
64 N971a548520364ac2b1b70e8e0e90bb70 schema:affiliation https://www.grid.ac/institutes/grid.18192.33
65 schema:familyName Shtamburg
66 schema:givenName V. V.
67 rdf:type schema:Person
68 Na860f5d3295e47e99447a3ee25940d62 schema:name State Scientific Institution “Institute for Single Crystals” of National Academy of Sciences of Ukraine, 60 Lenina Ave., 61001, Kharkiv, Ukraine
69 rdf:type schema:Organization
70 Na8c3150efa724936ba95e20503de6dcd schema:name doi
71 schema:value 10.1007/s10593-013-1363-5
72 rdf:type schema:PropertyValue
73 Nc3ea0041ea084fc2a21420fc2f420d9e rdf:first sg:person.015611422615.86
74 rdf:rest rdf:nil
75 Nc76a089563234a8fac930b85f47287fe schema:name N. N. Semenov Institute of Chemical Physics, 4 Kosygina St., 119991, Moscow, Russia
76 rdf:type schema:Organization
77 Ncf5a3ee69da248ef9bbbcb7eb5071d4d schema:volumeNumber 49
78 rdf:type schema:PublicationVolume
79 Ne54cfe757d034f4a805a7e2bbf4b69ea rdf:first N0510fe67aa4f448b8e7b4ab492f136e8
80 rdf:rest N45be4ddfb70f44dbbef5a24ed6220e1d
81 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
82 schema:name Engineering
83 rdf:type schema:DefinedTerm
84 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
85 schema:name Materials Engineering
86 rdf:type schema:DefinedTerm
87 sg:journal.1356886 schema:issn 0009-3122
88 1573-8353
89 schema:name Chemistry of Heterocyclic Compounds
90 rdf:type schema:Periodical
91 sg:person.01023575604.49 schema:affiliation N1440c6237cdf48e0947c37d6d80eb583
92 schema:familyName Shishkin
93 schema:givenName O. V.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01023575604.49
95 rdf:type schema:Person
96 sg:person.015611422615.86 schema:affiliation Nc76a089563234a8fac930b85f47287fe
97 schema:familyName Kostyanovsky
98 schema:givenName R. G.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015611422615.86
100 rdf:type schema:Person
101 sg:person.016173011573.64 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
102 schema:familyName Mazepa
103 schema:givenName A. V.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016173011573.64
105 rdf:type schema:Person
106 sg:person.0712120430.13 schema:affiliation Na860f5d3295e47e99447a3ee25940d62
107 schema:familyName Zubatyuk
108 schema:givenName R. I.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0712120430.13
110 rdf:type schema:Person
111 https://doi.org/10.1002/chir.20668 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035135721
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1016/0022-2836(71)90419-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008822204
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/j.mencom.2007.05.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014526373
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/j.mencom.2011.01.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035985217
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.mencom.2012.05.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005936477
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/s0040-4020(01)81665-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016725449
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/s0040-4020(01)87905-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041641687
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1016/s0040-4020(98)00197-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003990635
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1021/ja00331a053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055724017
128 rdf:type schema:CreativeWork
129 https://doi.org/10.1021/jm9607921 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055958030
130 rdf:type schema:CreativeWork
131 https://doi.org/10.1021/jo00275a027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055976768
132 rdf:type schema:CreativeWork
133 https://doi.org/10.1070/mc2006v016n04abeh002195 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018019999
134 rdf:type schema:CreativeWork
135 https://doi.org/10.1070/mc2006v016n06abeh002382 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011902960
136 rdf:type schema:CreativeWork
137 https://www.grid.ac/institutes/grid.18192.33 schema:alternateName Kharkiv Polytechnic Institute
138 schema:name National Technical University, Kharkiv Polytechnic Institute, 21 Frunze St., 61002, Kharkiv, Ukraine
139 rdf:type schema:Organization
140 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
141 schema:name A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, 86 Lyustdorfskaya Road, 65080, Odessa, Ukraine
142 rdf:type schema:Organization
143 https://www.grid.ac/institutes/grid.445406.7 schema:alternateName Ukrainian State University of Chemical Technology
144 schema:name Ukrainian State University of Chemical Technologies, 8 Gagarin Ave., 49005, Dnipropetrovsk, Ukraine
145 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...