Reduction of 7-R derivatives of 7H-tris[1,2,5]oxa-diazolo[3,4-b:3′,4′-d:3″,4″-f]azepine 1-oxide with furoxan ring opening. preparation of 4-R-4H-bis-[1,2,5]oxadiazolo[3,4-b:3′,4′-f]azepine-8,9-diamines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-09-26

AUTHORS

A. I. Stepanov, D. V. Dashko, A. A. Astrat’ev

ABSTRACT

It was shown that the reduction of derivatives of 7-R-7H-tris[1,2,5]oxadiazolo[3,4-b:3′,4′-d:3″,4″-f]azepine 1-oxide by hydrazine hydrate or hydrogen in the presence of palladium on carbon is accompanied by opening of the furoxan ring of the starting compound to the two amino groups and leads to the production of 4-R-4H-bis[1,2,5]oxadiazolo[3,4-b:3′,4′-f]azepine-8,9-diamines. Some chemical properties of the obtained diamino compounds are discussed. More... »

PAGES

1068-1081

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-013-1345-7

DOI

http://dx.doi.org/10.1007/s10593-013-1345-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015923945


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Stepanov", 
        "givenName": "A. I.", 
        "id": "sg:person.012710331673.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710331673.17"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dashko", 
        "givenName": "D. V.", 
        "id": "sg:person.015676233673.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015676233673.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Special Design and Construction Bureau SDCB \u201cTechnolog\u201d, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Astrat\u2019ev", 
        "givenName": "A. A.", 
        "id": "sg:person.0766314406.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0766314406.10"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s00542-013-1833-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051494334", 
          "https://doi.org/10.1007/s00542-013-1833-9"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-09-26", 
    "datePublishedReg": "2013-09-26", 
    "description": "It was shown that the reduction of derivatives of 7-R-7H-tris[1,2,5]oxadiazolo[3,4-b:3\u2032,4\u2032-d:3\u2033,4\u2033-f]azepine 1-oxide by hydrazine hydrate or hydrogen in the presence of palladium on carbon is accompanied by opening of the furoxan ring of the starting compound to the two amino groups and leads to the production of 4-R-4H-bis[1,2,5]oxadiazolo[3,4-b:3\u2032,4\u2032-f]azepine-8,9-diamines. Some chemical properties of the obtained diamino compounds are discussed.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-013-1345-7", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "49"
      }
    ], 
    "keywords": [
      "reduction of derivatives", 
      "presence of palladium", 
      "starting compound", 
      "hydrazine hydrate", 
      "furoxan ring", 
      "diamino compounds", 
      "amino groups", 
      "ring opening", 
      "chemical properties", 
      "diamine", 
      "compounds", 
      "derivatives", 
      "palladium", 
      "hydrogen", 
      "hydrate", 
      "preparation", 
      "carbon", 
      "ring", 
      "properties", 
      "reduction", 
      "presence", 
      "opening", 
      "group", 
      "production"
    ], 
    "name": "Reduction of 7-R derivatives of 7H-tris[1,2,5]oxa-diazolo[3,4-b:3\u2032,4\u2032-d:3\u2033,4\u2033-f]azepine 1-oxide with furoxan ring opening. preparation of 4-R-4H-bis-[1,2,5]oxadiazolo[3,4-b:3\u2032,4\u2032-f]azepine-8,9-diamines", 
    "pagination": "1068-1081", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1015923945"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-013-1345-7"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-013-1345-7", 
      "https://app.dimensions.ai/details/publication/pub.1015923945"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T17:01", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_584.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-013-1345-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1345-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1345-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1345-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1345-7'


 

This table displays all metadata directly associated to this object as RDF triples.

99 TRIPLES      21 PREDICATES      49 URIs      40 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-013-1345-7 schema:about anzsrc-for:03
2 anzsrc-for:0399
3 schema:author Nf55f5776257a48ac82a4fed447e89863
4 schema:citation sg:pub.10.1007/s00542-013-1833-9
5 schema:datePublished 2013-09-26
6 schema:datePublishedReg 2013-09-26
7 schema:description It was shown that the reduction of derivatives of 7-R-7H-tris[1,2,5]oxadiazolo[3,4-b:3′,4′-d:3″,4″-f]azepine 1-oxide by hydrazine hydrate or hydrogen in the presence of palladium on carbon is accompanied by opening of the furoxan ring of the starting compound to the two amino groups and leads to the production of 4-R-4H-bis[1,2,5]oxadiazolo[3,4-b:3′,4′-f]azepine-8,9-diamines. Some chemical properties of the obtained diamino compounds are discussed.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N5f6d4c290eaa4630ba85aceb5235c968
11 Nc5e044099aed420ca755fc4d9db5dfaf
12 sg:journal.1429545
13 schema:keywords amino groups
14 carbon
15 chemical properties
16 compounds
17 derivatives
18 diamine
19 diamino compounds
20 furoxan ring
21 group
22 hydrate
23 hydrazine hydrate
24 hydrogen
25 opening
26 palladium
27 preparation
28 presence
29 presence of palladium
30 production
31 properties
32 reduction
33 reduction of derivatives
34 ring
35 ring opening
36 starting compound
37 schema:name Reduction of 7-R derivatives of 7H-tris[1,2,5]oxa-diazolo[3,4-b:3′,4′-d:3″,4″-f]azepine 1-oxide with furoxan ring opening. preparation of 4-R-4H-bis-[1,2,5]oxadiazolo[3,4-b:3′,4′-f]azepine-8,9-diamines
38 schema:pagination 1068-1081
39 schema:productId N8afa95539129439ab033ce8917fd8259
40 Nacf20b59c92849caadb4a7ec1261c021
41 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015923945
42 https://doi.org/10.1007/s10593-013-1345-7
43 schema:sdDatePublished 2022-08-04T17:01
44 schema:sdLicense https://scigraph.springernature.com/explorer/license/
45 schema:sdPublisher N55bcd7e798304375b04643e3d28c13ea
46 schema:url https://doi.org/10.1007/s10593-013-1345-7
47 sgo:license sg:explorer/license/
48 sgo:sdDataset articles
49 rdf:type schema:ScholarlyArticle
50 N2b716f9064c74aaf9c97ee63a2fabcf6 rdf:first sg:person.015676233673.01
51 rdf:rest N30b8a7ea61a9434dbb96f724ba57e652
52 N30b8a7ea61a9434dbb96f724ba57e652 rdf:first sg:person.0766314406.10
53 rdf:rest rdf:nil
54 N55bcd7e798304375b04643e3d28c13ea schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 N5f6d4c290eaa4630ba85aceb5235c968 schema:volumeNumber 49
57 rdf:type schema:PublicationVolume
58 N8afa95539129439ab033ce8917fd8259 schema:name dimensions_id
59 schema:value pub.1015923945
60 rdf:type schema:PropertyValue
61 Nacf20b59c92849caadb4a7ec1261c021 schema:name doi
62 schema:value 10.1007/s10593-013-1345-7
63 rdf:type schema:PropertyValue
64 Nc5e044099aed420ca755fc4d9db5dfaf schema:issueNumber 7
65 rdf:type schema:PublicationIssue
66 Nf55f5776257a48ac82a4fed447e89863 rdf:first sg:person.012710331673.17
67 rdf:rest N2b716f9064c74aaf9c97ee63a2fabcf6
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
72 schema:name Other Chemical Sciences
73 rdf:type schema:DefinedTerm
74 sg:journal.1429545 schema:issn 0132-6244
75 1573-8353
76 schema:name Chemistry of Heterocyclic Compounds
77 schema:publisher Springer Nature
78 rdf:type schema:Periodical
79 sg:person.012710331673.17 schema:affiliation grid-institutes:None
80 schema:familyName Stepanov
81 schema:givenName A. I.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710331673.17
83 rdf:type schema:Person
84 sg:person.015676233673.01 schema:affiliation grid-institutes:None
85 schema:familyName Dashko
86 schema:givenName D. V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015676233673.01
88 rdf:type schema:Person
89 sg:person.0766314406.10 schema:affiliation grid-institutes:None
90 schema:familyName Astrat’ev
91 schema:givenName A. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0766314406.10
93 rdf:type schema:Person
94 sg:pub.10.1007/s00542-013-1833-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051494334
95 https://doi.org/10.1007/s00542-013-1833-9
96 rdf:type schema:CreativeWork
97 grid-institutes:None schema:alternateName Special Design and Construction Bureau SDCB “Technolog”, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia
98 schema:name Special Design and Construction Bureau SDCB “Technolog”, 33-A Sovetskii Ave., 192076, Saint Petersburg, Russia
99 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...