Reaction of 7-phenyl-7H-pyrazolo-[3,4-d][1,2,3]triazin-4-ol with thionyl chloride View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-09

AUTHORS

B. M. Khutova, S. V. Klyuchko, A. O. Gurenko, A. N. Vasilenko, E. B. Rusanov, V. S. Brovarets

ABSTRACT

The reaction of 7-phenyl-7H-pyrazolo[3,4-d][1,2,3]triazin-4-ol with thionyl chloride has been studied in the presence and absence of dimethyl formamide. It was found that heating the compound with thionyl chloride in the absence of dimethyl formamide gave 5-amino-1-phenyl-1H-pyrazole-4-carboxylic acid chloride and in its presence a mixture of 5-chloro-N-formyl-1-phenyl-1H-pyrazole-4-carboxamide, 5-chloro-1-phenyl-1H-pyrazole-4-carboxamide, and 4-chloro-6-(5-chloro-1-phenyl-1H-pyrazol-4-yl)-1-phenyl-1H-pyrazolo[3,4-d]pyrimidine.

PAGES

922-929

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-013-1327-9

DOI

http://dx.doi.org/10.1007/s10593-013-1327-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010511711


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biochemistry and Cell Biology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biological Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Bioorganic Chemistry and Petrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.424920.9", 
          "name": [
            "Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khutova", 
        "givenName": "B. M.", 
        "id": "sg:person.016060743253.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016060743253.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Bioorganic Chemistry and Petrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.424920.9", 
          "name": [
            "Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Klyuchko", 
        "givenName": "S. V.", 
        "id": "sg:person.015035075453.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015035075453.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Bioorganic Chemistry and Petrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.424920.9", 
          "name": [
            "Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gurenko", 
        "givenName": "A. O.", 
        "id": "sg:person.014704175071.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014704175071.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Bioorganic Chemistry and Petrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.424920.9", 
          "name": [
            "Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vasilenko", 
        "givenName": "A. N.", 
        "id": "sg:person.016162601147.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016162601147.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "E. B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Bioorganic Chemistry and Petrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.424920.9", 
          "name": [
            "Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brovarets", 
        "givenName": "V. S.", 
        "id": "sg:person.010072133553.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010072133553.61"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.ejmech.2011.11.038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004606691"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2007.03.030", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012536025"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2009.06.024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012810758"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570190602", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016844603"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570190602", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016844603"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570230141", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019078695"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570230141", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019078695"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.660410138", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020770667"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.660410138", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020770667"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2009.11.050", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027425221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570450211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043112057"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570450211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043112057"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmc.2012.01.032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045529251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2009.12.042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047785251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm00378a019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055945538"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-09", 
    "datePublishedReg": "2013-09-01", 
    "description": "The reaction of 7-phenyl-7H-pyrazolo[3,4-d][1,2,3]triazin-4-ol with thionyl chloride has been studied in the presence and absence of dimethyl formamide. It was found that heating the compound with thionyl chloride in the absence of dimethyl formamide gave 5-amino-1-phenyl-1H-pyrazole-4-carboxylic acid chloride and in its presence a mixture of 5-chloro-N-formyl-1-phenyl-1H-pyrazole-4-carboxamide, 5-chloro-1-phenyl-1H-pyrazole-4-carboxamide, and 4-chloro-6-(5-chloro-1-phenyl-1H-pyrazol-4-yl)-1-phenyl-1H-pyrazolo[3,4-d]pyrimidine.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10593-013-1327-9", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "49"
      }
    ], 
    "name": "Reaction of 7-phenyl-7H-pyrazolo-[3,4-d][1,2,3]triazin-4-ol with thionyl chloride", 
    "pagination": "922-929", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "32140c8ec45b9f0d314cff62ef23e68d0f7fac8b5ca719f763a36737e97b46bd"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-013-1327-9"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010511711"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-013-1327-9", 
      "https://app.dimensions.ai/details/publication/pub.1010511711"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000511.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10593-013-1327-9"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1327-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1327-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1327-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-013-1327-9'


 

This table displays all metadata directly associated to this object as RDF triples.

132 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-013-1327-9 schema:about anzsrc-for:06
2 anzsrc-for:0601
3 schema:author N3f16c4c8587643e1867b9e7a468c5be0
4 schema:citation https://doi.org/10.1002/hlca.660410138
5 https://doi.org/10.1002/jhet.5570190602
6 https://doi.org/10.1002/jhet.5570230141
7 https://doi.org/10.1002/jhet.5570450211
8 https://doi.org/10.1016/j.bmc.2012.01.032
9 https://doi.org/10.1016/j.ejmech.2007.03.030
10 https://doi.org/10.1016/j.ejmech.2009.06.024
11 https://doi.org/10.1016/j.ejmech.2009.11.050
12 https://doi.org/10.1016/j.ejmech.2009.12.042
13 https://doi.org/10.1016/j.ejmech.2011.11.038
14 https://doi.org/10.1021/jm00378a019
15 schema:datePublished 2013-09
16 schema:datePublishedReg 2013-09-01
17 schema:description The reaction of 7-phenyl-7H-pyrazolo[3,4-d][1,2,3]triazin-4-ol with thionyl chloride has been studied in the presence and absence of dimethyl formamide. It was found that heating the compound with thionyl chloride in the absence of dimethyl formamide gave 5-amino-1-phenyl-1H-pyrazole-4-carboxylic acid chloride and in its presence a mixture of 5-chloro-N-formyl-1-phenyl-1H-pyrazole-4-carboxamide, 5-chloro-1-phenyl-1H-pyrazole-4-carboxamide, and 4-chloro-6-(5-chloro-1-phenyl-1H-pyrazol-4-yl)-1-phenyl-1H-pyrazolo[3,4-d]pyrimidine.
18 schema:genre research_article
19 schema:inLanguage en
20 schema:isAccessibleForFree false
21 schema:isPartOf N9d75c0dae3f14a23b10029b8256c9667
22 Nf6ea899ed9114fb2a5efd94a8e3aa386
23 sg:journal.1356886
24 schema:name Reaction of 7-phenyl-7H-pyrazolo-[3,4-d][1,2,3]triazin-4-ol with thionyl chloride
25 schema:pagination 922-929
26 schema:productId N1c65915c0ec94d6ca8112b219506ec7e
27 N5ee7ee28fc2c4eb2849c598cffe067b9
28 Nbb424fc40d9b4b97ab0b11992560bbd5
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010511711
30 https://doi.org/10.1007/s10593-013-1327-9
31 schema:sdDatePublished 2019-04-10T19:08
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher N29c1b679d5ad449ca24264526ff1f768
34 schema:url http://link.springer.com/10.1007%2Fs10593-013-1327-9
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N1c65915c0ec94d6ca8112b219506ec7e schema:name doi
39 schema:value 10.1007/s10593-013-1327-9
40 rdf:type schema:PropertyValue
41 N1dd6a147dd3c4d399c4ecaf7e3368fc9 rdf:first sg:person.010072133553.61
42 rdf:rest rdf:nil
43 N29c1b679d5ad449ca24264526ff1f768 schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 N29e8a747a63c42bdb08eb0e228af3184 rdf:first sg:person.016162601147.84
46 rdf:rest Nee3f7f8caebe4d0d890c1622b6cc830c
47 N3f16c4c8587643e1867b9e7a468c5be0 rdf:first sg:person.016060743253.54
48 rdf:rest N9da366884cc840159ec6b8ef8186042b
49 N5ee7ee28fc2c4eb2849c598cffe067b9 schema:name dimensions_id
50 schema:value pub.1010511711
51 rdf:type schema:PropertyValue
52 N9d75c0dae3f14a23b10029b8256c9667 schema:volumeNumber 49
53 rdf:type schema:PublicationVolume
54 N9da366884cc840159ec6b8ef8186042b rdf:first sg:person.015035075453.55
55 rdf:rest Naa30088776db49f0b26ca5bb66edfb61
56 Naa30088776db49f0b26ca5bb66edfb61 rdf:first sg:person.014704175071.52
57 rdf:rest N29e8a747a63c42bdb08eb0e228af3184
58 Nbb424fc40d9b4b97ab0b11992560bbd5 schema:name readcube_id
59 schema:value 32140c8ec45b9f0d314cff62ef23e68d0f7fac8b5ca719f763a36737e97b46bd
60 rdf:type schema:PropertyValue
61 Nee3f7f8caebe4d0d890c1622b6cc830c rdf:first sg:person.01247600537.28
62 rdf:rest N1dd6a147dd3c4d399c4ecaf7e3368fc9
63 Nf6ea899ed9114fb2a5efd94a8e3aa386 schema:issueNumber 6
64 rdf:type schema:PublicationIssue
65 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
66 schema:name Biological Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
69 schema:name Biochemistry and Cell Biology
70 rdf:type schema:DefinedTerm
71 sg:journal.1356886 schema:issn 0009-3122
72 1573-8353
73 schema:name Chemistry of Heterocyclic Compounds
74 rdf:type schema:Periodical
75 sg:person.010072133553.61 schema:affiliation https://www.grid.ac/institutes/grid.424920.9
76 schema:familyName Brovarets
77 schema:givenName V. S.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010072133553.61
79 rdf:type schema:Person
80 sg:person.01247600537.28 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
81 schema:familyName Rusanov
82 schema:givenName E. B.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
84 rdf:type schema:Person
85 sg:person.014704175071.52 schema:affiliation https://www.grid.ac/institutes/grid.424920.9
86 schema:familyName Gurenko
87 schema:givenName A. O.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014704175071.52
89 rdf:type schema:Person
90 sg:person.015035075453.55 schema:affiliation https://www.grid.ac/institutes/grid.424920.9
91 schema:familyName Klyuchko
92 schema:givenName S. V.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015035075453.55
94 rdf:type schema:Person
95 sg:person.016060743253.54 schema:affiliation https://www.grid.ac/institutes/grid.424920.9
96 schema:familyName Khutova
97 schema:givenName B. M.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016060743253.54
99 rdf:type schema:Person
100 sg:person.016162601147.84 schema:affiliation https://www.grid.ac/institutes/grid.424920.9
101 schema:familyName Vasilenko
102 schema:givenName A. N.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016162601147.84
104 rdf:type schema:Person
105 https://doi.org/10.1002/hlca.660410138 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020770667
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1002/jhet.5570190602 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016844603
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1002/jhet.5570230141 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019078695
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1002/jhet.5570450211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043112057
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1016/j.bmc.2012.01.032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045529251
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/j.ejmech.2007.03.030 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012536025
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/j.ejmech.2009.06.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012810758
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.ejmech.2009.11.050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027425221
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/j.ejmech.2009.12.042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047785251
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/j.ejmech.2011.11.038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004606691
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1021/jm00378a019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055945538
126 rdf:type schema:CreativeWork
127 https://www.grid.ac/institutes/grid.424920.9 schema:alternateName Institute of Bioorganic Chemistry and Petrochemistry
128 schema:name Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., 02660, Kyiv, Ukraine
129 rdf:type schema:Organization
130 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
131 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv, Ukraine
132 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...