Conversions of 7-aryl-7H-pyrazolo[3,4-d]-[1,2,3]triazin-4-ols by the action of phosphorus pentoxide, pentasulfide, and oxychloride View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11-08

AUTHORS

B. M. Khutova, S. V. Klyuchko, A. O. Gurenko, A. N. Vasilenko, A. G. Balya, E. B. Rusanov, V. S. Brovarets

ABSTRACT

The interaction of 7-aryl-7H-pyrazolo[3,4-d][1,2,3]triazin-4-ols with phosphorus pentoxide or pentasulfide leads to the formation of 6-(5-amino-1-aryl-1H-pyrazol-4-yl)-1-aryl-1H,4H-pyrazolo[3,4-d][1,3]oxazin-4-ones and 6-(5-amino-1-aryl-1H-pyrazol-4-yl)-1-aryl-1H,4H-pyrazolo[3,4-d][1,3]thiazine-4-thiones, respectively. Reaction with phosphorus oxychloride leads to 1-aryl-5-chloro-1H-pyrazole-4-carbonyl chlorides, from which the corresponding amides, hydrazides, and substituted 1,3,4-oxadiazoles were synthesized.

PAGES

1251-1262

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-012-1128-6

DOI

http://dx.doi.org/10.1007/s10593-012-1128-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003281671


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