Synthesis of chiral glycolurils from (S)-(+)- and (R)-(-)-1-sec-butyl-3-methylurea View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-08

AUTHORS

R. G. Kostyanovsky, G. K. Kadorkina, I. S. Bushmarinov, K. A. Lyssenko, I. I. Chervin, V. R. Kostyanovsky

ABSTRACT

Chiral dialkyl- and tetraalkylglycolurils have been obtained using chiral (S)-(+)- and (R)-(-)-1-sec-butyl-3-methylurea as starting materials. The diastereomer (S)-(+)-2,6-di-sec-butyl-4,8-dimethyl-2,4,6,8-tetraazabicyclo[3.3.0]-octane-3,7-dione was separated into stereoisomers, for the higher melting of which the absolute configuration was determined as (S,S,S,S) by X-ray structural analysis.

PAGES

766-772

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-012-1055-6

DOI

http://dx.doi.org/10.1007/s10593-012-1055-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016695914


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