Signs of formation and chemical evolution of zwitterions in the reaction of 1-methylimidazole with cyanophenylacetylene and benzaldehyde View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-02

AUTHORS

L. V. Andriyankova, K. V. Belyaeva, L. P. Nikitina, A. G. Mal’kina, T. I. Vakul’skaya, S. S. Khutsishvili, L. M. Sinegovskaya, B. A. Trofimov

ABSTRACT

Primary monitoring of the three-component reaction of 1-methylimidazole with cyanophenylacetylene and benzaldehyde by EPR, UV, NMR, and IR spectroscopy has been carried out. Experimental evidence has been obtained for the formation of zwitterions and carbenes of the imidazole series as intermediates of a new functionalization reaction of the imidazole ring leading to 2-benzoyl-3-(1-methyl-1H-imidazol-2-yl)-3-phenylpropanenitrile. More... »

PAGES

1390-1394

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-012-0926-1

DOI

http://dx.doi.org/10.1007/s10593-012-0926-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053717806


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