Photo- and thermochromic spiranes 32*. Synthesis and photochromism of 3-methyl-4-oxospiro(2,3-dihydronaphtho-[2,1-e]-1,3-oxazine-2,2'-[2H]-chromenes) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

E. L. Mukhanov, Yu. S. Alekseenko, B. S. Lukyanov, V. I. Minkin, S. O. Bezuglyi, A. N. Utenyshev, V. V. Tkachev, and S. M. Aldoshin

ABSTRACT

Spiropyrans of the naphthoxazinone series have been obtained containing various substituents in the [2H]-chromene portion of the molecule. The spatial structure of a spiropyran containing ortho-positioned hydroxyl and formyl groups was established by X-ray structural analysis. The photochromic properties of the obtained compounds have been studied.

PAGES

219-227

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-009-0253-3

DOI

http://dx.doi.org/10.1007/s10593-009-0253-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006244624


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mukhanov", 
        "givenName": "E. L.", 
        "id": "sg:person.011131600067.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011131600067.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.465325.3", 
          "name": [
            "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Alekseenko", 
        "givenName": "Yu. S.", 
        "id": "sg:person.016241061451.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016241061451.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lukyanov", 
        "givenName": "B. S.", 
        "id": "sg:person.012117331203.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012117331203.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.465325.3", 
          "name": [
            "Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia", 
            "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minkin", 
        "givenName": "V. I.", 
        "id": "sg:person.07535265367.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07535265367.87"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.465325.3", 
          "name": [
            "Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bezuglyi", 
        "givenName": "S. O.", 
        "id": "sg:person.07646015171.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07646015171.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Utenyshev", 
        "givenName": "A. N.", 
        "id": "sg:person.015236213545.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tkachev", 
        "givenName": "V. V.", 
        "id": "sg:person.012075437173.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012075437173.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "and S. M.", 
        "type": "Person"
      }
    ], 
    "datePublished": "2009-02", 
    "datePublishedReg": "2009-02-01", 
    "description": "Spiropyrans of the naphthoxazinone series have been obtained containing various substituents in the [2H]-chromene portion of the molecule. The spatial structure of a spiropyran containing ortho-positioned hydroxyl and formyl groups was established by X-ray structural analysis. The photochromic properties of the obtained compounds have been studied.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-009-0253-3", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "keywords": [
      "X-ray structural analysis", 
      "photochromic properties", 
      "formyl group", 
      "spiropyran", 
      "structural analysis", 
      "substituents", 
      "photochromism", 
      "hydroxyl", 
      "ortho", 
      "compounds", 
      "synthesis", 
      "molecules", 
      "properties", 
      "structure", 
      "series", 
      "photos", 
      "spatial structure", 
      "group", 
      "analysis", 
      "portion"
    ], 
    "name": "Photo- and thermochromic spiranes 32*. Synthesis and photochromism of 3-methyl-4-oxospiro(2,3-dihydronaphtho-[2,1-e]-1,3-oxazine-2,2'-[2H]-chromenes)", 
    "pagination": "219-227", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006244624"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-009-0253-3"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-009-0253-3", 
      "https://app.dimensions.ai/details/publication/pub.1006244624"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:35", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_490.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-009-0253-3"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-009-0253-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-009-0253-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-009-0253-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-009-0253-3'


 

This table displays all metadata directly associated to this object as RDF triples.

132 TRIPLES      20 PREDICATES      45 URIs      37 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-009-0253-3 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N30459e7705364cd3ab790a003b5b3284
4 schema:datePublished 2009-02
5 schema:datePublishedReg 2009-02-01
6 schema:description Spiropyrans of the naphthoxazinone series have been obtained containing various substituents in the [2H]-chromene portion of the molecule. The spatial structure of a spiropyran containing ortho-positioned hydroxyl and formyl groups was established by X-ray structural analysis. The photochromic properties of the obtained compounds have been studied.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N12e2f970044049f5b269899fcdaeda84
10 N28559e6a824c4d2a921f10d57536010b
11 sg:journal.1429545
12 schema:keywords X-ray structural analysis
13 analysis
14 compounds
15 formyl group
16 group
17 hydroxyl
18 molecules
19 ortho
20 photochromic properties
21 photochromism
22 photos
23 portion
24 properties
25 series
26 spatial structure
27 spiropyran
28 structural analysis
29 structure
30 substituents
31 synthesis
32 schema:name Photo- and thermochromic spiranes 32*. Synthesis and photochromism of 3-methyl-4-oxospiro(2,3-dihydronaphtho-[2,1-e]-1,3-oxazine-2,2'-[2H]-chromenes)
33 schema:pagination 219-227
34 schema:productId N34996310ad8848ad9995a7f0f2a7e20f
35 N9e283f422c7e4900b168c08135d4786f
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006244624
37 https://doi.org/10.1007/s10593-009-0253-3
38 schema:sdDatePublished 2022-10-01T06:35
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher Nacf7c6c812fa4690afea5eafe99bd90d
41 schema:url https://doi.org/10.1007/s10593-009-0253-3
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N12e2f970044049f5b269899fcdaeda84 schema:issueNumber 2
46 rdf:type schema:PublicationIssue
47 N1eed5fecd92e4e76901a5814953030b9 rdf:first sg:person.07535265367.87
48 rdf:rest N86d6ab4136354d55b3c124107c414a24
49 N22d14bf7969741ff92cffc436f908095 rdf:first N95e21c891c3d44e2ba1124e10b313748
50 rdf:rest rdf:nil
51 N28559e6a824c4d2a921f10d57536010b schema:volumeNumber 45
52 rdf:type schema:PublicationVolume
53 N30459e7705364cd3ab790a003b5b3284 rdf:first sg:person.011131600067.63
54 rdf:rest Nbd3c5379fb4d4a8da16ff1d19fcd91f0
55 N34996310ad8848ad9995a7f0f2a7e20f schema:name dimensions_id
56 schema:value pub.1006244624
57 rdf:type schema:PropertyValue
58 N3fbee9072d994888b7b4fe1572e34ee1 rdf:first sg:person.012075437173.40
59 rdf:rest N22d14bf7969741ff92cffc436f908095
60 N86d6ab4136354d55b3c124107c414a24 rdf:first sg:person.07646015171.44
61 rdf:rest Nec526e00fef244c7be5f0820498b2ee3
62 N95e21c891c3d44e2ba1124e10b313748 schema:affiliation grid-institutes:grid.418949.9
63 schema:familyName Aldoshin
64 schema:givenName and S. M.
65 rdf:type schema:Person
66 N9e283f422c7e4900b168c08135d4786f schema:name doi
67 schema:value 10.1007/s10593-009-0253-3
68 rdf:type schema:PropertyValue
69 Nacf7c6c812fa4690afea5eafe99bd90d schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 Nbd3c5379fb4d4a8da16ff1d19fcd91f0 rdf:first sg:person.016241061451.15
72 rdf:rest Nfdf4728d1aa0474f8a9afe03767a6bbd
73 Nec526e00fef244c7be5f0820498b2ee3 rdf:first sg:person.015236213545.72
74 rdf:rest N3fbee9072d994888b7b4fe1572e34ee1
75 Nfdf4728d1aa0474f8a9afe03767a6bbd rdf:first sg:person.012117331203.93
76 rdf:rest N1eed5fecd92e4e76901a5814953030b9
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
81 schema:name Organic Chemistry
82 rdf:type schema:DefinedTerm
83 sg:journal.1429545 schema:issn 0132-6244
84 1573-8353
85 schema:name Chemistry of Heterocyclic Compounds
86 schema:publisher Springer Nature
87 rdf:type schema:Periodical
88 sg:person.011131600067.63 schema:affiliation grid-institutes:grid.182798.d
89 schema:familyName Mukhanov
90 schema:givenName E. L.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011131600067.63
92 rdf:type schema:Person
93 sg:person.012075437173.40 schema:affiliation grid-institutes:grid.418949.9
94 schema:familyName Tkachev
95 schema:givenName V. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012075437173.40
97 rdf:type schema:Person
98 sg:person.012117331203.93 schema:affiliation grid-institutes:grid.182798.d
99 schema:familyName Lukyanov
100 schema:givenName B. S.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012117331203.93
102 rdf:type schema:Person
103 sg:person.015236213545.72 schema:affiliation grid-institutes:grid.418949.9
104 schema:familyName Utenyshev
105 schema:givenName A. N.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72
107 rdf:type schema:Person
108 sg:person.016241061451.15 schema:affiliation grid-institutes:grid.465325.3
109 schema:familyName Alekseenko
110 schema:givenName Yu. S.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016241061451.15
112 rdf:type schema:Person
113 sg:person.07535265367.87 schema:affiliation grid-institutes:grid.465325.3
114 schema:familyName Minkin
115 schema:givenName V. I.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07535265367.87
117 rdf:type schema:Person
118 sg:person.07646015171.44 schema:affiliation grid-institutes:grid.465325.3
119 schema:familyName Bezuglyi
120 schema:givenName S. O.
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07646015171.44
122 rdf:type schema:Person
123 grid-institutes:grid.182798.d schema:alternateName Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia
124 schema:name Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia
125 rdf:type schema:Organization
126 grid-institutes:grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia
127 schema:name Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow region, Russia
128 rdf:type schema:Organization
129 grid-institutes:grid.465325.3 schema:alternateName Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia
130 schema:name Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia
131 Southern Scientific Center, Russian Academy of Sciences, 344090, Rostov-on-Don, Russia
132 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...