Novel ecdysteroid analogs with oxygen-containing heterocycles in the steroid skeleton View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-09

AUTHORS

V. N. Odinokov, I. V. Galyautdinov, A. Sh. Ibragimova, N. A. Veskina, L. M. Khalilov, F. M. Dolgushin, Z. A. Starikova

ABSTRACT

The reaction of ecdysteroids (20-hydroxyecdysone and its acetonides) with lithium in liquid ammonia gave novel analogs with an oxetane 9α,14α-oxacycle in the steroid skeleton. In aqueous alcohol solution the 9,14-oxa analogs rearrange to the more stable 9α,13α-oxa analogs through a 1,2-migration of the 18-Me group from the C-13 to the C-14 atom. More... »

PAGES

1077-1091

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-008-0157-7

DOI

http://dx.doi.org/10.1007/s10593-008-0157-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036586511


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Odinokov", 
        "givenName": "V. N.", 
        "id": "sg:person.012441113233.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012441113233.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Galyautdinov", 
        "givenName": "I. V.", 
        "id": "sg:person.01273330653.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01273330653.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ibragimova", 
        "givenName": "A. Sh.", 
        "id": "sg:person.07715230762.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07715230762.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Veskina", 
        "givenName": "N. A.", 
        "id": "sg:person.014325232637.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014325232637.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khalilov", 
        "givenName": "L. M.", 
        "id": "sg:person.01250305306.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250305306.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dolgushin", 
        "givenName": "F. M.", 
        "id": "sg:person.01267101640.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2008-09", 
    "datePublishedReg": "2008-09-01", 
    "description": "The reaction of ecdysteroids (20-hydroxyecdysone and its acetonides) with lithium in liquid ammonia gave novel analogs with an oxetane 9\u03b1,14\u03b1-oxacycle in the steroid skeleton. In aqueous alcohol solution the 9,14-oxa analogs rearrange to the more stable 9\u03b1,13\u03b1-oxa analogs through a 1,2-migration of the 18-Me group from the C-13 to the C-14 atom.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-008-0157-7", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1358699", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "44"
      }
    ], 
    "keywords": [
      "novel analogues", 
      "group", 
      "analogues", 
      "steroid skeleton", 
      "ecdysteroids", 
      "oxygen-containing heterocycles", 
      "skeleton", 
      "ecdysteroid analogues", 
      "aqueous alcohol solutions", 
      "alcohol solution", 
      "lithium", 
      "liquid ammonia", 
      "oxa analogues", 
      "reaction", 
      "C-13", 
      "heterocycles", 
      "oxacycles", 
      "atoms", 
      "ammonia", 
      "rearranges", 
      "solution", 
      "reaction of ecdysteroids", 
      "analogs rearrange", 
      "C-14 atom", 
      "Novel ecdysteroid analogs"
    ], 
    "name": "Novel ecdysteroid analogs with oxygen-containing heterocycles in the steroid skeleton", 
    "pagination": "1077-1091", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1036586511"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-008-0157-7"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-008-0157-7", 
      "https://app.dimensions.ai/details/publication/pub.1036586511"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_460.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-008-0157-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0157-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0157-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0157-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0157-7'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      51 URIs      43 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-008-0157-7 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N1b1f0421214041cfa60e7ced984ba692
4 schema:datePublished 2008-09
5 schema:datePublishedReg 2008-09-01
6 schema:description The reaction of ecdysteroids (20-hydroxyecdysone and its acetonides) with lithium in liquid ammonia gave novel analogs with an oxetane 9α,14α-oxacycle in the steroid skeleton. In aqueous alcohol solution the 9,14-oxa analogs rearrange to the more stable 9α,13α-oxa analogs through a 1,2-migration of the 18-Me group from the C-13 to the C-14 atom.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N69c12516e8e547a5b2b3f42b9028054f
11 N763c2ce7312d4c94b01df488350c4762
12 sg:journal.1358699
13 schema:keywords C-13
14 C-14 atom
15 Novel ecdysteroid analogs
16 alcohol solution
17 ammonia
18 analogs rearrange
19 analogues
20 aqueous alcohol solutions
21 atoms
22 ecdysteroid analogues
23 ecdysteroids
24 group
25 heterocycles
26 liquid ammonia
27 lithium
28 novel analogues
29 oxa analogues
30 oxacycles
31 oxygen-containing heterocycles
32 reaction
33 reaction of ecdysteroids
34 rearranges
35 skeleton
36 solution
37 steroid skeleton
38 schema:name Novel ecdysteroid analogs with oxygen-containing heterocycles in the steroid skeleton
39 schema:pagination 1077-1091
40 schema:productId N7003fd07df884cdc9f116441a08d1484
41 Na3d5fb88e61f433daddc294945d98818
42 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036586511
43 https://doi.org/10.1007/s10593-008-0157-7
44 schema:sdDatePublished 2021-12-01T19:19
45 schema:sdLicense https://scigraph.springernature.com/explorer/license/
46 schema:sdPublisher N346397f6b2144925b9a430293641c156
47 schema:url https://doi.org/10.1007/s10593-008-0157-7
48 sgo:license sg:explorer/license/
49 sgo:sdDataset articles
50 rdf:type schema:ScholarlyArticle
51 N1b1f0421214041cfa60e7ced984ba692 rdf:first sg:person.012441113233.31
52 rdf:rest N50b19ac18d8b426b95ede271903e30cd
53 N2ed410409e4044d09c64f24e27229ce0 rdf:first sg:person.07715230762.26
54 rdf:rest Nfde224a754a94263bbed0d91495c5d87
55 N346397f6b2144925b9a430293641c156 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 N49ff4c0af5284145a87b3310e45384d8 rdf:first sg:person.014473641160.05
58 rdf:rest rdf:nil
59 N50b19ac18d8b426b95ede271903e30cd rdf:first sg:person.01273330653.12
60 rdf:rest N2ed410409e4044d09c64f24e27229ce0
61 N69c12516e8e547a5b2b3f42b9028054f schema:issueNumber 9
62 rdf:type schema:PublicationIssue
63 N7003fd07df884cdc9f116441a08d1484 schema:name doi
64 schema:value 10.1007/s10593-008-0157-7
65 rdf:type schema:PropertyValue
66 N763c2ce7312d4c94b01df488350c4762 schema:volumeNumber 44
67 rdf:type schema:PublicationVolume
68 N97d54f5356104fcc8c7586cb09b7a67f rdf:first sg:person.01250305306.93
69 rdf:rest Nd80214e5f0c94f42b27c7fa9105eaaf5
70 Na3d5fb88e61f433daddc294945d98818 schema:name dimensions_id
71 schema:value pub.1036586511
72 rdf:type schema:PropertyValue
73 Nd80214e5f0c94f42b27c7fa9105eaaf5 rdf:first sg:person.01267101640.70
74 rdf:rest N49ff4c0af5284145a87b3310e45384d8
75 Nfde224a754a94263bbed0d91495c5d87 rdf:first sg:person.014325232637.27
76 rdf:rest N97d54f5356104fcc8c7586cb09b7a67f
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
81 schema:name Physical Chemistry (incl. Structural)
82 rdf:type schema:DefinedTerm
83 sg:journal.1358699 schema:issn 0132-6244
84 1573-8353
85 schema:name Chemistry of Heterocyclic Compounds
86 schema:publisher Springer Nature
87 rdf:type schema:Periodical
88 sg:person.012441113233.31 schema:affiliation grid-institutes:grid.4886.2
89 schema:familyName Odinokov
90 schema:givenName V. N.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012441113233.31
92 rdf:type schema:Person
93 sg:person.01250305306.93 schema:affiliation grid-institutes:grid.4886.2
94 schema:familyName Khalilov
95 schema:givenName L. M.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250305306.93
97 rdf:type schema:Person
98 sg:person.01267101640.70 schema:affiliation grid-institutes:grid.4886.2
99 schema:familyName Dolgushin
100 schema:givenName F. M.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70
102 rdf:type schema:Person
103 sg:person.01273330653.12 schema:affiliation grid-institutes:grid.4886.2
104 schema:familyName Galyautdinov
105 schema:givenName I. V.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01273330653.12
107 rdf:type schema:Person
108 sg:person.014325232637.27 schema:affiliation grid-institutes:grid.4886.2
109 schema:familyName Veskina
110 schema:givenName N. A.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014325232637.27
112 rdf:type schema:Person
113 sg:person.014473641160.05 schema:affiliation grid-institutes:grid.4886.2
114 schema:familyName Starikova
115 schema:givenName Z. A.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
117 rdf:type schema:Person
118 sg:person.07715230762.26 schema:affiliation grid-institutes:grid.4886.2
119 schema:familyName Ibragimova
120 schema:givenName A. Sh.
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07715230762.26
122 rdf:type schema:Person
123 grid-institutes:grid.4886.2 schema:alternateName A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
124 Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia
125 schema:name A. N. Nesmeyanov Institute for Organoelemental Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
126 Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...