Quinazolines 1. Synthesis and chemical reactions of 6-chlorosulfonyl-quinazoline-2,4-diones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-03

AUTHORS

R. Sh. Kuryazov, N. S. Mukhamedov, Kh. M. Shakhidoyatov

ABSTRACT

Treatment of quinazoline-2,4-dione and its symmetrical 1,3-dialkyl derivatives with chlorosulfonic acid gave the corresponding 6-chlorosulfonylquinazoline-2,4-diones. Reaction of the compounds obtained with nucleophilic agents (water, ammonia, aliphatic and cyclic amines) gave the corresponding free 2,4-dioxoquinazoline-6-sulfonic acids, 6-sulfamidoquinazoline-2,4-diones, and 2,4-dioxoquinazoline-6-sulfonic acid amides.

PAGES

324

References to SciGraph publications

  • 2002-03. Benzazoles. 1. Acylation of Benzothiazolin-2-ones by Aromatic Acid Chlorides Using Small Amounts of Zinc Chloride in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2002-04. Benzazoles. 2. Relative Activity of Catalysts and 4-Substituted Benzoyl Chlorides in the Acylation of Benzothiazolin-2-ones in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1970. Biological Activity in the Quinazolone Series in PROGRESS IN DRUG RESEARCH / FORTSCHRITTE DER ARZNEIMITTELFORSCHUNG / PROGRÈS DES RECHERCHES PHARMACEUTIQUES
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10593-008-0048-y

    DOI

    http://dx.doi.org/10.1007/s10593-008-0048-y

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1000552418


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Organic Chemistry", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan", 
              "id": "http://www.grid.ac/institutes/grid.419209.7", 
              "name": [
                "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kuryazov", 
            "givenName": "R. Sh.", 
            "id": "sg:person.013536432213.54", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013536432213.54"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan", 
              "id": "http://www.grid.ac/institutes/grid.419209.7", 
              "name": [
                "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Mukhamedov", 
            "givenName": "N. S.", 
            "id": "sg:person.01230255577.17", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01230255577.17"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan", 
              "id": "http://www.grid.ac/institutes/grid.419209.7", 
              "name": [
                "S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shakhidoyatov", 
            "givenName": "Kh. M.", 
            "id": "sg:person.015706066705.62", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1023/a:1015647606680", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036881433", 
              "https://doi.org/10.1023/a:1015647606680"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-0348-7075-7_5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035462691", 
              "https://doi.org/10.1007/978-3-0348-7075-7_5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1016083322553", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045478405", 
              "https://doi.org/10.1023/a:1016083322553"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2008-03", 
        "datePublishedReg": "2008-03-01", 
        "description": "Treatment of quinazoline-2,4-dione and its symmetrical 1,3-dialkyl derivatives with chlorosulfonic acid gave the corresponding 6-chlorosulfonylquinazoline-2,4-diones. Reaction of the compounds obtained with nucleophilic agents (water, ammonia, aliphatic and cyclic amines) gave the corresponding free 2,4-dioxoquinazoline-6-sulfonic acids, 6-sulfamidoquinazoline-2,4-diones, and 2,4-dioxoquinazoline-6-sulfonic acid amides.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/s10593-008-0048-y", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1358699", 
            "issn": [
              "0132-6244", 
              "1573-8353"
            ], 
            "name": "Chemistry of Heterocyclic Compounds", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "44"
          }
        ], 
        "keywords": [
          "chlorosulfonic acid", 
          "nucleophilic agents", 
          "chemical reactions", 
          "acid amides", 
          "reaction", 
          "acid", 
          "amides", 
          "synthesis", 
          "compounds", 
          "derivatives", 
          "agents", 
          "treatment"
        ], 
        "name": "Quinazolines 1. Synthesis and chemical reactions of 6-chlorosulfonyl-quinazoline-2,4-diones", 
        "pagination": "324", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1000552418"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s10593-008-0048-y"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s10593-008-0048-y", 
          "https://app.dimensions.ai/details/publication/pub.1000552418"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-01-01T18:19", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_476.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/s10593-008-0048-y"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0048-y'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0048-y'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0048-y'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-008-0048-y'


     

    This table displays all metadata directly associated to this object as RDF triples.

    96 TRIPLES      22 PREDICATES      41 URIs      30 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s10593-008-0048-y schema:about anzsrc-for:03
    2 anzsrc-for:0305
    3 schema:author Nc8b819b0e96141a395248e412ebf0fc8
    4 schema:citation sg:pub.10.1007/978-3-0348-7075-7_5
    5 sg:pub.10.1023/a:1015647606680
    6 sg:pub.10.1023/a:1016083322553
    7 schema:datePublished 2008-03
    8 schema:datePublishedReg 2008-03-01
    9 schema:description Treatment of quinazoline-2,4-dione and its symmetrical 1,3-dialkyl derivatives with chlorosulfonic acid gave the corresponding 6-chlorosulfonylquinazoline-2,4-diones. Reaction of the compounds obtained with nucleophilic agents (water, ammonia, aliphatic and cyclic amines) gave the corresponding free 2,4-dioxoquinazoline-6-sulfonic acids, 6-sulfamidoquinazoline-2,4-diones, and 2,4-dioxoquinazoline-6-sulfonic acid amides.
    10 schema:genre article
    11 schema:inLanguage en
    12 schema:isAccessibleForFree false
    13 schema:isPartOf N399f4074aa6e4a01a74b545e7f298e0e
    14 Nffcacbbd412e4156b74a8e3d7f6b754f
    15 sg:journal.1358699
    16 schema:keywords acid
    17 acid amides
    18 agents
    19 amides
    20 chemical reactions
    21 chlorosulfonic acid
    22 compounds
    23 derivatives
    24 nucleophilic agents
    25 reaction
    26 synthesis
    27 treatment
    28 schema:name Quinazolines 1. Synthesis and chemical reactions of 6-chlorosulfonyl-quinazoline-2,4-diones
    29 schema:pagination 324
    30 schema:productId N2db62e5c93b74cfba69b11f816724fea
    31 Nddb6a822d928483a923869c3f85e21ec
    32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000552418
    33 https://doi.org/10.1007/s10593-008-0048-y
    34 schema:sdDatePublished 2022-01-01T18:19
    35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    36 schema:sdPublisher N9caf06584fe64d9e971004c1d833dbcd
    37 schema:url https://doi.org/10.1007/s10593-008-0048-y
    38 sgo:license sg:explorer/license/
    39 sgo:sdDataset articles
    40 rdf:type schema:ScholarlyArticle
    41 N06ccb7ef76f94bfb93063e30c3331f8b rdf:first sg:person.015706066705.62
    42 rdf:rest rdf:nil
    43 N1aefee80688d4742a43b5fee1faa6259 rdf:first sg:person.01230255577.17
    44 rdf:rest N06ccb7ef76f94bfb93063e30c3331f8b
    45 N2db62e5c93b74cfba69b11f816724fea schema:name doi
    46 schema:value 10.1007/s10593-008-0048-y
    47 rdf:type schema:PropertyValue
    48 N399f4074aa6e4a01a74b545e7f298e0e schema:volumeNumber 44
    49 rdf:type schema:PublicationVolume
    50 N9caf06584fe64d9e971004c1d833dbcd schema:name Springer Nature - SN SciGraph project
    51 rdf:type schema:Organization
    52 Nc8b819b0e96141a395248e412ebf0fc8 rdf:first sg:person.013536432213.54
    53 rdf:rest N1aefee80688d4742a43b5fee1faa6259
    54 Nddb6a822d928483a923869c3f85e21ec schema:name dimensions_id
    55 schema:value pub.1000552418
    56 rdf:type schema:PropertyValue
    57 Nffcacbbd412e4156b74a8e3d7f6b754f schema:issueNumber 3
    58 rdf:type schema:PublicationIssue
    59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    60 schema:name Chemical Sciences
    61 rdf:type schema:DefinedTerm
    62 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
    63 schema:name Organic Chemistry
    64 rdf:type schema:DefinedTerm
    65 sg:journal.1358699 schema:issn 0132-6244
    66 1573-8353
    67 schema:name Chemistry of Heterocyclic Compounds
    68 schema:publisher Springer Nature
    69 rdf:type schema:Periodical
    70 sg:person.01230255577.17 schema:affiliation grid-institutes:grid.419209.7
    71 schema:familyName Mukhamedov
    72 schema:givenName N. S.
    73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01230255577.17
    74 rdf:type schema:Person
    75 sg:person.013536432213.54 schema:affiliation grid-institutes:grid.419209.7
    76 schema:familyName Kuryazov
    77 schema:givenName R. Sh.
    78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013536432213.54
    79 rdf:type schema:Person
    80 sg:person.015706066705.62 schema:affiliation grid-institutes:grid.419209.7
    81 schema:familyName Shakhidoyatov
    82 schema:givenName Kh. M.
    83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62
    84 rdf:type schema:Person
    85 sg:pub.10.1007/978-3-0348-7075-7_5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035462691
    86 https://doi.org/10.1007/978-3-0348-7075-7_5
    87 rdf:type schema:CreativeWork
    88 sg:pub.10.1023/a:1015647606680 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036881433
    89 https://doi.org/10.1023/a:1015647606680
    90 rdf:type schema:CreativeWork
    91 sg:pub.10.1023/a:1016083322553 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045478405
    92 https://doi.org/10.1023/a:1016083322553
    93 rdf:type schema:CreativeWork
    94 grid-institutes:grid.419209.7 schema:alternateName S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan
    95 schema:name S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences Republic of Uzbekistan, 700170, Tashkent, Uzbekistan
    96 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...