Photo-and thermochromic spiranes 30*. Comparative study by X-ray structural analysis of the structure of spiropyrans of the indoline series containing ... View Full Text


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Article Info

DATE

2008-02

AUTHORS

B. S. Lukyanov, A. N. Utenyshev, V. V. Tkachev, S. M. Aldoshin, V. I. Minkin, M. B. Lukyanova, Yu. S. Alekseenko

ABSTRACT

The structure of an indoline spiropyran of molecular formula C29H33NO2 has been studied by X-ray crystallographic analysis. Structural parameters have been determined for this spiropyran, containing a condensed furan fragment with a tert-butyl group, in comparison with the structure of other spiropyrans of this series. The observation in the absorption spectrum of a photoinduced cis-cis isomer is linked with its stabilization by the steric effect of the bulky tert-butyl group and the strength of barriers at 77 K. More... »

PAGES

163-169

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-008-0034-4

DOI

http://dx.doi.org/10.1007/s10593-008-0034-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024452608


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